Date
2019-06-26Metadata
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Aufsatz
Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation
Abstract
A series of bis‐[3]ferrocenophanes of the general type Fe(C5H4E’)2E−E(E'C5H4)2Fe (E=P, SiH and E’=PtBu, NneoPentyl, NSi(CH3)3) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X‐ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.
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Gefördert durch den Publikationsfonds der Universität KasselCitation
@article{doi:10.17170/kobra-20191213869,
author={Isenberg, Stefan and Weller, Stefan and Kargin, Denis and Valić, Srećko and Schwederski, Brigitte and Kelemen, Zsolt and Bruhn, Clemens and Krekić, Kristijan and Maurer, Martin and Feil, Christoph M. and Nieger, Martin and Gudat, Dietrich and Nyulászi, László and Pietschnig, Rudolf},
title={Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation},
journal={ChemistryOpen},
year={2019}
}
0500 Oax 0501 Text $btxt$2rdacontent 0502 Computermedien $bc$2rdacarrier 1100 2019$n2019 1500 1/eng 2050 ##0##http://hdl.handle.net/123456789/11394 3000 Isenberg, Stefan 3010 Weller, Stefan 3010 Kargin, Denis 3010 Valić, Srećko 3010 Schwederski, Brigitte 3010 Kelemen, Zsolt 3010 Bruhn, Clemens 3010 Krekić, Kristijan 3010 Maurer, Martin 3010 Feil, Christoph M. 3010 Nieger, Martin 3010 Gudat, Dietrich 3010 Nyulászi, László 3010 Pietschnig, Rudolf 4000 Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation / Isenberg, Stefan 4030 4060 Online-Ressource 4085 ##0##=u http://nbn-resolving.de/http://hdl.handle.net/123456789/11394=x R 4204 \$dAufsatz 4170 7136 ##0##http://hdl.handle.net/123456789/11394
<resource xsi:schemaLocation="http://datacite.org/schema/kernel-2.2 http://schema.datacite.org/meta/kernel-2.2/metadata.xsd"> 2019-12-13T13:08:10Z 2019-12-13T13:08:10Z 2019-06-26 doi:10.17170/kobra-20191213869 http://hdl.handle.net/123456789/11394 Gefördert durch den Publikationsfonds der Universität Kassel eng Urheberrechtlich geschützt https://rightsstatements.org/page/InC/1.0/ phosphorus ferrocene homolytic bond cleavage thermolysis radicals 540 Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation Aufsatz A series of bis‐[3]ferrocenophanes of the general type Fe(C5H4E’)2E−E(E'C5H4)2Fe (E=P, SiH and E’=PtBu, NneoPentyl, NSi(CH3)3) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X‐ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations. open access Isenberg, Stefan Weller, Stefan Kargin, Denis Valić, Srećko Schwederski, Brigitte Kelemen, Zsolt Bruhn, Clemens Krekić, Kristijan Maurer, Martin Feil, Christoph M. Nieger, Martin Gudat, Dietrich Nyulászi, László Pietschnig, Rudolf doi:10.1002/open.201900182 publishedVersion ISSN 2191-1363 Issue 10 ChemistryOpen 1235-1243 Volume 8 </resource>
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