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dc.date.accessioned2020-07-20T08:11:37Z
dc.date.available2020-07-20T08:11:37Z
dc.date.issued2020-01-27
dc.identifierdoi:10.17170/kobra-202007171462
dc.identifier.urihttp://hdl.handle.net/123456789/11647
dc.language.isoengeng
dc.rightsNamensnennung 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectCarbene homologueseng
dc.subjectMetalloceneseng
dc.subjectOxidative additioneng
dc.subjectTineng
dc.subjectX-ray diffractioneng
dc.subject.ddc540
dc.titleOxidation Reactions of the N-Heterocyclic Stannylenes [𝘰-C₆H₄ (NSi𝑡BuMe₂)]₂Sn and [{Fe(η⁵ -C₅H₄ -NSi𝑡BuMe₂)₂}Sn] with Sulfur, Selenium, and Diphenyl Diselenideeng
dc.typeAufsatz
dcterms.abstractThe N‐heterocyclic stannylenes [{Fe(η$^5$‐C$_5$H$_4$‐NSi𝑡 BuMe$_2$)$_2$}Sn] (1 ) and [𝘰‐C$_6$H$_4$(NSi𝑡 BuMe$_2$)]$_2$Sn (2 ) were prepared in one‐pot reactions from SnCl$_2$, LiN(SiMe$_3$)$_2$, and the corresponding diamine, viz. [Fe(η$^5$‐C$_5$H$_4$‐NHSi𝑡 BuMe$_2$)$_2$] and 𝘰‐C$_6$H$_4$(NSiH𝘵 BuMe$_2$)$_2$, respectively. Oxidative addition reactions of 1 and 2 with S$_8$ and Se$_8$, respectively, afforded the corresponding 1,3,2,4‐dithiadistannetanes ((1 S$_2$), (2 S$_2$)), and 1,3,2,4‐diselenadistannetanes [(1 Se)$_2$, (2 Se)$_2$]. The reactions of 1 and 2 with PhSeSePh respectively furnished 1 (SePh)$_2$ and 2 (SePh)$_2$. The crystal structures of 𝘰‐C$_6$H$_4$(NSiH𝑡 BuMe$_2$)$_2$, 1, 2, ( 1 S)$_2$, (2 S)$_2$, (1 Se)$_2$, (2 Se)$_2$, 1 (SePh)$_2$, and 2 (SePh)$_2$ were determined by single‐crystal X‐ray diffraction. Stannylene 2 shows a chain‐like aggregation in the solid state due to intermolecular Sn⋯arene interactions. A short intramolecular CH⋯Se contact compatible with a hydrogen bond was observed for (1 Se)$_2$.eng
dcterms.accessRightsopen access
dcterms.creatorGuthardt, Robin
dcterms.creatorBachmann, Dennis
dcterms.creatorBruhn, Clemens
dcterms.creatorSiemeling, Ulrich
dc.relation.doidoi:10.1002/zaac.201900335
dc.subject.swdCarbeneger
dc.subject.swdHomologe <Chemie>ger
dc.subject.swdRöntgendiffraktometrieger
dc.type.versionpublishedVersion
dcterms.source.identifierEISSN 1521-3749
dcterms.source.issueIssue 13
dcterms.source.journalJournal of Inorganic and General Chemistry : ZAACeng
dcterms.source.pageinfo761-768
dcterms.source.volumeVolume 646
kup.iskupfalse


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