Cross-π-conjugated enediyne with multioptic metal binding sites
| dc.date.accessioned | 2020-11-20T10:10:15Z | |
| dc.date.available | 2020-11-20T10:10:15Z | |
| dc.date.issued | 2020-10-20 | |
| dc.identifier | doi:10.17170/kobra-202011202227 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/12006 | |
| dc.description.sponsorship | Gefördert durch den Publikationsfonds der Universität Kassel | |
| dc.language.iso | eng | |
| dc.rights | Namensnennung 3.0 International | * |
| dc.rights.uri | http://creativecommons.org/licenses/by/3.0/ | * |
| dc.subject.ddc | 540 | |
| dc.title | Cross-π-conjugated enediyne with multioptic metal binding sites | eng |
| dc.type | Aufsatz | |
| dcterms.abstract | The synthesis of an enediyne molecule functionlized with different metal coordination sites in a cross-pconjugated fashion is reported. Using Pd-mediated cross-coupling reactions, 2,20-bipyridine units were attached at the periphery of diazafluorenemethylidene to obtain a multitopic ligand. UV-vis spectrosopic investigations along with electrochemical analyses reveal electronic communication along the conjugated path reflected in red-shifted absorption spectra and shifts of reduction potentials. The properties of the ligand could be manipulated by coordinating [Ru(bpy)2]2+ fragments at all three coordination spheres of the molecule while the different complexing imine moieties serve as possible coordination sites for various metal centres. | eng |
| dcterms.accessRights | open access | |
| dcterms.creator | Nauroozi, Djawed | |
| dcterms.creator | Wurster, Benjamin | |
| dcterms.creator | Faust, Rüdiger | |
| dc.relation.doi | doi:10.1039/d0ra06320g | |
| dc.subject.swd | Chemie | ger |
| dc.subject.swd | Technische Chemie | ger |
| dc.subject.swd | Elektrochemie | ger |
| dc.type.version | publishedVersion | |
| dcterms.source.identifier | EISSN 2046-2069 | |
| dcterms.source.issue | Issue 63 | |
| dcterms.source.journal | RSC Advances | eng |
| dcterms.source.pageinfo | 38612-38616 | |
| dcterms.source.volume | Volume 10 | |
| kup.iskup | false |
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