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Polyurethane-Based Gel Electrolyte for Application in Flexible Electrochromic Devices

dc.date.accessioned2022-08-24T07:37:36Z
dc.date.available2022-08-24T07:37:36Z
dc.date.issued2022-06-28
dc.identifierdoi:10.17170/kobra-202208236733ger
dc.identifier.urihttp://hdl.handle.net/123456789/14099
dc.description.sponsorshipGefördert durch den Publikationsfonds der Universität Kasselger
dc.language.isoeng
dc.rightsNamensnennung 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectelectrolyteeng
dc.subjectelectrochromic deviceeng
dc.subjectflexibleeng
dc.subject.ddc660
dc.titlePolyurethane-Based Gel Electrolyte for Application in Flexible Electrochromic Deviceseng
dc.typeAufsatz
dcterms.abstractFor the application in flexible electrochromic devices (ECDs) on plastic substrates, a new polyurethane-based gel electrolyte was manufactured. In this context, the curing behavior and the influence of the proportion of solvent and salt on the ion conductivity as well as the optical and mechanical properties were investigated. Furthermore, the stoichiometric ratio of the polyurethane matrix was varied to influence the ion conductivity. As an isocyanate component, the aliphatic difunctional polyisocyanate prepolymer, synthesized by Hexamethylen-1,6-diisocyanat (HDI), was chosen since the resulting polyurethane is considered to be particularly lightfast, color-stable and temperature-resistant and therefore frequently used for paints and coatings. As polyol a trifunctional polyetherpolyol was selected to form a wide-meshed crosslinked matrix to achieve a mechanically stable but flexible electrolyte, that enables the processing and bending of film-based ECDs. The additives amount and the matrix stoichiometric ratio affected the curing behavior and curability. The salt content had almost no influence on the measured properties in the chosen experimental space. Solvent content had a great influence on ion conductivity and mechanical properties. An understoichiometric ratio of the polyurethane matrix (0.85) increases the ion conductivity and the mechanical flexibility, but also the optical properties in a negative manner. The best specific ion conductivity with 10-⁵ S/cm was reached with an understoichiometric ratio of 0.85 and a high solvent content (30 wt%). Concluding, due to its high flexibility and transmittance, color neutrality and sufficient ion conductivity, the application of the researched electroyte in ECDs might be suitable. A demonstrator ECD was successfully manufactured and conducted.eng
dcterms.accessRightsopen access
dcterms.creatorJohannes, Christopher
dcterms.creatorHartung, Michael
dcterms.creatorHeim, Hans-Peter
dc.relation.doidoi:10.3390/polym14132636
dc.subject.swdElektrolytger
dc.subject.swdPolyurethaneger
dc.subject.swdKunststoffverarbeitungger
dc.subject.swdChemische Reaktionger
dc.subject.swdElektrochemieger
dc.subject.swdPolyelektrolytger
dc.subject.swdAggregatzustandger
dc.subject.swdIonenleitungger
dc.subject.swdPolyethylenglykoleger
dc.type.versionpublishedVersion
dcterms.source.identifiereissn:2073-4360
dcterms.source.issueIssue 13
dcterms.source.journalPolymerseng
dcterms.source.volumeVolume 14
kup.iskupfalse
dcterms.source.articlenumber2636


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