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Characterization of films and film-forming solutions of chitosan/thermoplastic rice starch associations: Role of starch oxidation and plasticizer type in the molecular interactions

dc.date.accessioned2024-02-01T17:34:31Z
dc.date.available2024-02-01T17:34:31Z
dc.date.issued2023-09-29
dc.identifierdoi:10.17170/kobra-202312209251
dc.identifier.urihttp://hdl.handle.net/123456789/15426
dc.description.sponsorshipGefördert im Rahmen des Projekts DEALger
dc.language.isoeng
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectchitosaneng
dc.subjectrheologyeng
dc.subjectrice starcheng
dc.subjectthermoplasticeng
dc.subject.ddc540
dc.subject.ddc660
dc.titleCharacterization of films and film-forming solutions of chitosan/thermoplastic rice starch associations: Role of starch oxidation and plasticizer type in the molecular interactionseng
dc.typeAufsatz
dcterms.abstractPolysaccharide films are alternative sources to replace fossil-based compounds. This study aimed to use rice starch modified by gelatinization and oxidation processes. Different properties were observed after blending it with chitosan and polyols, as evaluated on the film-forming solutions by rheology. The interaction between chitosan and oxidized starch appeared higher, as the plasticizers exhibited a low effect on the rheological behavior. Polyols played an essential role in chitosan/gelatinized associations, driven by the number of OH groups. Films were evaluated by thermogravimetry (TGA), differential scanning calorimetry (DSC), water vapor permeability (WVP), water solubility, and tensile tests. The effect of the plasticizer type on chitosan/gelatinized starch was related to an increase in the temperature of the endothermic peak observed by DSC, confirming the role of hydroxyl groups of polyols in the polymer–polymer chain associations. The WVP and solubility decreased with starch oxidation due to increased chitosan–starch interactions. The decrease in tensile strength with adding polyols was correlated to reduced direct interactions between chitosan and starch chains. A drop of about 77% in elongation at break was observed in chitosan/oxidized starch film. On the other hand, elongation at break increased by around 14% in films with sorbitol (SO).eng
dcterms.accessRightsopen access
dcterms.creatorHorn, Marilia Marta
dcterms.creatorMartins, Virginia da Conceição Amaro
dcterms.creatorPlepis, Ana Maria de Guzzi
dc.relation.doidoi:10.1002/pen.26513
dc.relation.projectidGrant Number: 140362/2008-8 ; Grant Number: Finance Code 001eng
dc.subject.swdChitosanger
dc.subject.swdRheologieger
dc.subject.swdReisstärkeger
dc.subject.swdThermoplastger
dc.subject.swdPhysikalisch-chemische Eigenschaftger
dc.type.versionpublishedVersion
dcterms.source.identifiereissn:1548-2634
dcterms.source.issueIssue 12
dcterms.source.journalPolymer Engineering & Scienceeng
dcterms.source.pageinfo4127-4139
dcterms.source.volumeVolume 63
kup.iskupfalse


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Attribution-NonCommercial-NoDerivatives 4.0 International
Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivatives 4.0 International