Zur Kurzanzeige

Transformation and Leaching Simulation of 6:2 and 8:2 diPAP and Related Metabolites in Unsaturated Soil Column Studies with MACRO

dc.date.accessioned2024-07-02T12:54:23Z
dc.date.available2024-07-02T12:54:23Z
dc.date.issued2023-10-14
dc.identifierdoi:10.17170/kobra-2024070210451
dc.identifier.urihttp://hdl.handle.net/123456789/15892
dc.description.sponsorshipMinisterium für Umwelt, Klima und Energiewirtschaft Baden-Württembergger
dc.language.isoeng
dc.rightsNamensnennung 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectPFASeng
dc.subjectdiPAPeng
dc.subjectMACROeng
dc.subject.ddc540
dc.titleTransformation and Leaching Simulation of 6:2 and 8:2 diPAP and Related Metabolites in Unsaturated Soil Column Studies with MACROeng
dc.typeAufsatz
dcterms.abstractPFAS (perfluoroalkyl substances) are widespread in the environment and are found in almost every medium. Besides persistent PFAS, their transforming precursors gained attention since they may be a reservoir for persistent PFAS in soil. Only little information is available about the behavior of these precursors and the simultaneous leaching of their transformation products. However, this information is urgently needed to improve estimates of contamination levels. For this purpose, two precursors and their non-degradable metabolites were simulated using the MACRO model, with parameter values optimized using the evolutionary algorithm caRamel. A constant first-order transformation rate did not adequately represent the leaching of transformation products, but a variable transformation rate that decreased at the date of an equilibrium soil moisture provided a good representation of the precursor transformation and leaching of transformation products. The results are new evidence that variable environmental parameters such as soil moisture may affect the transformation rate of precursors. The simulation study is a step towards describing the behavior of PFAS precursors through physically-based models.eng
dcterms.accessRightsopen access
dcterms.creatorWeidemann, Eva
dcterms.creatorGaßmann, Matthias
dc.relation.doidoi:10.1007/s10666-023-09936-8
dc.relation.projectidFKZ BWPFC19002
dc.relation.projectidFKZ BWPFC19004
dc.relation.projectidFKZ BWPFC19005
dc.relation.projectidKZ BWPFC19006
dc.subject.swdPerfluorverbindungenger
dc.subject.swdMetabolitger
dc.subject.swdMACROger
dc.subject.swdBodensäuleger
dc.subject.swdStudieger
dc.type.versionpublishedVersion
dcterms.source.identifiereissn:1573-2967
dcterms.source.issueIssue 2
dcterms.source.journalEnvironmental Modeling & Assessmenteng
dcterms.source.pageinfo223 - 234
dcterms.source.volumeVolume 29
kup.iskupfalse


Dateien zu dieser Ressource

Thumbnail
Name:
license_rdf
Größe:
908Bytes
Format:
application/rdf+xml
Öffnen
Thumbnail
Name:
s10666_023_09936_8.pdf
Größe:
1.831Mb
Format:
PDF
Öffnen

Das Dokument erscheint in:

Zur Kurzanzeige

Namensnennung 4.0 International
Solange nicht anders angezeigt, wird die Lizenz wie folgt beschrieben: Namensnennung 4.0 International