Date
2024-05-07Metadata
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Aufsatz
Discriminatory resonance energy transfer mediated by a chiral environment
Abstract
In this study, we delve into the crucial influence of and enhancement by chiral environments on the discriminatory capabilities of resonance energy transfer. Firstly, we scrutinize the impact of a macroscopic chiral medium enveloping the interacting molecules; secondly, we probe the effect of a chiral mediating molecule in close proximity to the system. Importantly, our findings demonstrate that chiral environments not only modulate pre-existing discriminatory effects but also introduce novel mechanisms for discrimination. Central to our research is the application of an innovative model for chiral local-field corrections, which unveils a remarkable distance-dependent inversion of the discrimination dynamics. Our study extends beyond the confines of any specific molecular system, offering a comprehensive discussion of these diverse effects, thereby providing insights with broader implications. Finally, we present a comparative analysis across all studied systems, illustrating our insights by employing 3-methyl-cyclopentanone as an example molecule.
Sponsorship
Gefördert im Rahmen eines Open-Access-Transformationsvertrags mit dem VerlagCitation
@article{doi:10.17170/kobra-2024080210633,
author={Franz, Janine Christine and Buhmann, Yoshi and Salam, Akbar},
title={Discriminatory resonance energy transfer mediated by a chiral environment},
journal={New Journal of Physics},
year={2024}
}
0500 Oax
0501 Text $btxt$2rdacontent
0502 Computermedien $bc$2rdacarrier
1100 2024$n2024
1500 1/eng
2050 ##0##http://hdl.handle.net/123456789/15956
3000 Franz, Janine Christine
3010 Buhmann, Yoshi
3010 Salam, Akbar
4000 Discriminatory resonance energy transfer mediated by a chiral environment / Franz, Janine Christine
4030
4060 Online-Ressource
4085 ##0##=u http://nbn-resolving.de/http://hdl.handle.net/123456789/15956=x R
4204 \$dAufsatz
4170
5550 {{Chiralität <Chemie>}}
5550 {{Energieübertragung}}
5550 {{Resonanzenergie}}
5550 {{Diskriminierung}}
7136 ##0##http://hdl.handle.net/123456789/15956
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