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Aufsatz
Kinematic dipole model for the anisotropy of quasimolecular X-rays
(1978)
For the angular dependence of quasimolecular X-ray emission in heavy ion colliding systems we present a semiclassical adiabatic model taking into account spontaneous dipole radiation. Using the most characteristic levels from a DFS-correlation diagram we are able to explain the behaviour of the observed anisotropy.
Aufsatz
Threshold behaviour of L x-ray excitation in Xe - Ag collisions
(1978)
In the collision system Xe - Ag, the thresholds for excitation of quasimolecular L radiation and characteristic Ag L radiation have been found to lie at about 5 MeV and 1 MeV, respectively. These results are discussed on the basis of ab initio calculations of the screened interaction potential and the electron-correlation diagram.
Aufsatz
Interpretation of noncharacteristic M X-rays in heavy colliding systems by selfconsistent relativistic molecular calculations
(1976)
The result of the first calculation of a self-consistent relativistic many electron correlation diagram ever done (for the system Au - I) leads to a good agreement of the spectral shape and position of the observed noncharacteristic X-rays within the quasi adiabatic model.
Aufsatz
Note on the quasimolecular M radiation in very heavy collision systems
(1976)
The quasimolecular M radiation emitted in collisions between Xe ions of up to 6 MeV energy and solid targets of Ta, Au, Pb and Bi, as well as a gaseous target of Pb(CH_3)_4, has been studied. Using a realistic theoretical correlation diagram, a semiquantitative explanation of the observed peak structure is given.
Aufsatz
Prediction of the azimuth angle dependence of the quasimolecular anisotropy in heavy ion collisions
(1979)
Within the quasimolecular (MO) kinematic dipole model we predict a strong dependence of the anisotropy of the MO radiation on the orientation of the heavy ion scattering plane relative to the direction of the photon detection plane.
Aufsatz
Predicted properties of the superheavy elements. III. Element 115, Eka-Bismuth
(1974)
Element 115 is expected to be in group V-a of the periodic table and have most stable oxidation states of I and III. The oxidation state of I, which plays a minor role in bismuth chemistry, should be a major factor in 115 chemistry. This change will arise because of the large relativistic splitting of the spherically symmetric 7p_l/2 shell from the 7P_3/2 shell. Element 115 will therefore have a single 7p_3/2 electron outside a 7p^2_1/2 closed shell. The magnitude of the first ionization energy and ionic radius suggest ...
Aufsatz
Predicted properties of the superheavy elements, II. Element 111, Eka-Gold
(1973)
The chemical properties of element 111, eka-gold, are predicted through the use of the periodic table, relativistic Hartee-Fock-Slater calculations, and various qualitative theories which have established their usefulness in understanding and correlating properties of molecules. The results indicate that element 111 will be like Au(III) in its chemistry with little or no tendency to show stability in the I or II states. There is a possibility that the 111 - ion, analogous to the auride ion, will be stable.
Aufsatz
Relativistic molecular calculations of superheavy molecules
(1979)
Relativistic molecular calculations within the Dirac-Slater scheme have been used in a study of the electronic structure of 6d-metal superheavy hexafluorides. The theoretical results are compared with calculations and measurements of the homolog 4d- and 5d-metal hexafluorides. Large spin-orbit splitting dominates the electronic structure and even has the same order of magnitude as the crystal-field splitting for the valence electrons for the superheavy molecules. Ionization energies have been calculated using a ...
Aufsatz
The continuation of the periodic table up to Z = 172.
(1970)
The chemical elements up to Z = 172 are calculated with a relativistic Hartree-Fock-Slater
program taking into account the effect of the extended nucleus. Predictions of the binding energies, the X-ray spectra and the number of electrons inside the nuclei are given for the inner electron shells.
The predicted chemical behaviour will be discussed for a11 elements between Z = 104-120 and compared with previous known extrapolations. For the elements Z = 121-172 predictions of their chemistry and a proposal for the ...
Aufsatz
Precise calculations of atomic electron binding energies in fermium
(1972)
The comparison between the experimental binding energies for the K, L, and M electrons for fermium and the results of our Dirac-Fock calculation, taking into account all tractable corrections, leads to agreement within about 20 eV. This shows that the present method of calculation is an adequate description of this problem and that nonlinear electrodynamical effects will not be present in nature or will be smaller than 1% compared to the values recently proposed. It is found that the energies of electronic transitions ...