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Aufsatz
Cross-Linked Hydrophobic Starch Granules in Blends with PLA
(2018-04-17)
The majority of native starch is used in the food sector and in the paper industry. Only a small amount is used in polymer engineering. One reason for the reluctance of the plastics processing industry to use starch as a filling material in polymer blends is the unsatisfactory mechanical behavior of starch when combined with thermoplastics. Another reason is the hydrophilicity of starch. In order to make these materials capable of competing, an amelioration of the mechanical properties is compulsory. By means of ...
Konferenzveröffentlichung
UV light irradiation of fibers in thermoplastic pultrusion for higher surface energy
(Society of Plastics Engineers, 2018)
Pultrusion is a common way to produce thermoplastic composites reinforced with different kinds of fibers. There are many different opportunities to improve the properties of a thermoplastic material. Different kind of fibers where pultruded in combination with different thermoplastic materials. The fiber content was set to 30wt% comparing the roving strain with the pultruded strain. UV-C light was used in the process to improve the fiber matrix adhesion. The pultruded strain was granulated and injection molded to ...
Aufsatz
Characterization of polyamide 6.10 composites incorporated with microcrystalline cellulose fiber: Effects of fiber loading and impact modifier
(2018-08-14)
Microcrystalline cellulose (MCC) fiber‐reinforced polyamide 6.10 (PA) composites were prepared in the presence of an impact modifier (IM), exxelor VA1803 (VA), by melt compounding process. Fiber loading was considered from 20 to 30 wt.%, whereas IM was varied from 2.0 to 5.0 wt.%. Composites were characterized by tensile test, impact test, dynamic thermal mechanical analysis (DTMA), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and X‐ray diffraction (XRD). Composites’ fractured surfaces ...
Konferenzveröffentlichung
Influence Of The Fiber-Matrix-Interaction On The Fracture Behavior Of Regenerated Cellulose Fiber Reinforced Polypropylene
(Society of Plastics Engineers, 2017)
This investigation focuses on the fiber-matrix-interaction of man-made cellulose fibers (RCF) in a PP matrix with an additional MAPP content using an energetic evaluation of the single fiber pull-out test (SFPT). Furthermore glass fibers were characterized for reference purposes. With the SFPT the interfacial shear strength (IFFS) and the critical fiber length (lc) as well as the consumed energy of a fiber pull-out and a fiber rupture were determined. In a following step the resulting values of lc were related to the ...
Aufsatz
Fabrication and characterization of ethylene–octene copolymer composites with ionic liquid functionalized carbon nanotubes
(2017-10-16)
Modification of multi-walled carbon nanotubes (MWCNTs) by means of imidazolium ionic liquid (IL) was performed. Structural characterization of funtionalized nanofillers (IL-f-MWCNTs) was made by means of Raman spectroscopy and transmission electron microscopy. MWCNTs and IL-f-MWCNTs were introduced within ethylene octane copolymer (EOC) with octene co-monomer content of 17% by using the masterbatch approach. The efficiency of the carbonaceous nanofiller distribution within the polymer matrix was characterized by means ...
Konferenzveröffentlichung
Blending CA with PBS to increase the bonding strength in two-component injection molding
(Society of Plastics Engineers, 2019)
Since CA shows no adhesive properties in the two-component injection molding process with bio based TPU, blends of CA and PBS were produced to decrease the interfacial tension between the materials. While the interfacial tension was calculated from the results of a drop shape analysis, the adhesion strength was measured in peel tests according to the guideline VDI 2019. The comparison of the results gave information about whether the drop shape analysis is a valid method to analyze the adhesive characteristics of ...
Konferenzveröffentlichung
Natural fiber reinforced technical (bio-) composites modified with halogen-free flame retardants
(Society of Plastics Engineers, 2019)
Under the aspect of sustainability and the use of alternative materials, engineering thermoplastics such as polybutylene terephthalate (PBT) will be reinforced with renewable raw materials such as regenerated cellulose fibers.
The University of Kassel is developing cellulose regenerated fiber reinforced technical thermoplastics in a state-funded project with further companies. Since pure natural fibers cannot withstand the high operating temperature of engineering thermoplastics (Ts>230°C), regenerated cellulose ...