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Cross-Linked Hydrophobic Starch Granules in Blends with PLA
(2018-04-17)
The majority of native starch is used in the food sector and in the paper industry. Only a small amount is used in polymer engineering. One reason for the reluctance of the plastics processing industry to use starch as a filling material in polymer blends is the unsatisfactory mechanical behavior of starch when combined with thermoplastics. Another reason is the hydrophilicity of starch. In order to make these materials capable of competing, an amelioration of the mechanical properties is compulsory. By means of ...
Aufsatz
Effects of aging on the stress-induced martensitic transformation and cyclic superelastic properties in Co-Ni-Ga shape memory alloy single crystals under compression
(2022)
Co-Ni-Ga shape memory alloys attracted scientific attention as promising candidate materials for damping applications at elevated temperatures, owing to excellent superelastic properties featuring a fully reversible stress-strain response up to temperatures as high as 500 °C. In the present work, the effect of aging treatments conducted in a wide range of aging temperatures and times, i.e. at 300–400 °C for 0.25–8.5 h, was investigated. It is shown that critical features of the martensitic transformation are strongly ...
Aufsatz
Additive manufacturing of Co-Ni-Ga high-temperature shape memory alloy - Processability 3 and phase transformation behavior
(2019)
Co-Ni-Ga high-temperature shape memory alloy is additively processed by selective laser melting for the first time. Reversiblemartensitic transformation of the as-built material is proven by differential scanning calorimetry. Microstructural analysis reveals a columnar-grained microstructure due to epitaxial solidification. Columnar-grained microstructures are characterized by a very low degree of constraints being beneficial for superior functional performance in numerous shape memory alloys. However, process-induced ...
Aufsatz
Investigations on Tightness of Polymer-Metal Hybrids in Environments with Thermal, Media, and Mechanical Loads
(2017-07-31)
With polymer-metal hybrids becoming more commonly used as structural components it was investigated how they perform in complex environments with combined thermal, media, and mechanical loads. Special attention was put on media tightness under said loads. This paper sums up the activities of the polymer technology research group of the University of Kassel on hybrids produced by overmolding metal inserts. Investigations concerning joint strength and influence of (cyclic) temperature loads and chemical corrosion on ...
Aufsatz
Mechanical Properties of Polydimethylsiloxane as a Function of the Amount and Type of Crosslinking Agent
(2017-06-13)
In this investigation, a high-consistency rubber (HCR) was mixed with five different, typically used crosslinking agents that are based on organic peroxide. Furthermore, the amount of crosslinking agent was varied in order to quantify the effect on the mechanical properties. All materials were processed in a hot pressing process, and, subsequently, post-cured. The properties were characterized by the measurement of the swelling ratio, shore A-hardness, rebound resilience and tensile test. We successfully proved that ...
Aufsatz
Microstructure of an additively manufactured Ti-Ta-Al alloy using novel pre-alloyed powder feedstock material
(2023-05-01)
Binary Ti-Ta and ternary Ti-Ta-Al alloys attracted considerable attention as new potential biomaterials and/or high-temperature shape memory alloys. However, conventional forming and manufacturing technologies of refractory based titanium alloys are difficult and cost-intensive, especially when complex shapes are required. Recently, additive manufacturing (AM) emerged as a suitable alternative and several studies exploited elemental powder mixing approaches to obtain a desired alloy and subsequently use it for complex ...
Aufsatz
Pathways towards grain boundary engineering for improved structural performance in polycrystalline Co-Ni-Ga shape memory alloys
(2018)
Co-Ni-Ga high-temperature shape memory alloys attracted a lot of scientific attention due to their superior functional material properties in recent years. In the single crystalline state Co-Ni-Ga HT-SMAs feature a good pseudoelastic response up to 500°C. However, in the polycrystalline condition Co-Ni-Ga suffers significant grain constraints and premature fracture at grain boundaries. In this regard, crystallographic orientation of the grain being involved as well as morphology and geometrical orientation of the ...
Aufsatz
Influence of ethylene oxide and gamma irradiation sterilization processes on the degradation behaviour of poly(lactic acid) (PLA) in the course of artificially accelerated aging
(2024-02-10)
To promote the application of bio-based materials in the field of medical technology, it is essential to conduct additional research, focusing on their long-term performance after sterilization. For this purpose, the study examines the aging behaviour of three poly(lactic-acid) (PLA) materials, sterilized with either ethylene oxide or gamma irradiation, over a two years aging period, in accordance with ASTM F1980-21. During these investigations, a direct correlation between moisture absorption and degradation progression ...
Aufsatz
Exploring the mechanical properties of additively manufactured carbon-rich zirconia 3D microarchitectures
(2023-07-11)
Two-photon lithography (TPL) is a promising technique for manufacturing ceramic microstructures with nanoscale resolution. The process relies on tailor-made precursor resins rich in metal–organic and organic constituents, which can lead to carbon-based residues incorporated within the ceramic microstructures. While these are generally considered unwanted impurities, our study reveals that the presence of carbon-rich residues in the form of graphitic and disordered carbon in tetragonal (t-) ZrO₂ can benefit the ...
Aufsatz
Influence of Cu Addition and Microstructural Configuration on the Creep Resistance and Mechanical Properties of an Fe-Based α/α′/α″ Superalloy
(2023-01-14)
Introducing Cu nanoparticles is an effective mechanism for strengthening and toughening Fe-based materials such as ultra-high-strength steels. Herein, the effect of Cu on the mechanical properties of a novel Fe-based α/α′/α″ superalloy is studied. Compared to a Cu-free reference alloy, nanoindentation reveals an increase in hardness, which was associated with the formation of Cu nanoparticles. Both alloys show room temperature (RT) compressive plastic strain at maximum stress greater than 8%, irrespective of the ...