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UV Pre-Treatment for Polycarbonate for Bonding LSR in a Multi-Component Injection Molding Process
(2019-03-01)
In this study, the influence of UVC radiation and the influence of ozone on the surface energy of specimens made of polycarbonate were investigated. In an additional step, the peeling resistance of silicone flaps, which were overmolded, onto pre-treated PC plates of multicomponent specimens were analyzed. For this purpose, the samples were exposed to UVC radiation for different lengths of time, ranging from 5 s to 3 600 s. To further evaluate the influence of the ozone created by the UVC in the presence of oxygen, ...
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Additive manufacturing of Co-Ni-Ga high-temperature shape memory alloy - Processability 3 and phase transformation behavior
(2019)
Co-Ni-Ga high-temperature shape memory alloy is additively processed by selective laser melting for the first time. Reversiblemartensitic transformation of the as-built material is proven by differential scanning calorimetry. Microstructural analysis reveals a columnar-grained microstructure due to epitaxial solidification. Columnar-grained microstructures are characterized by a very low degree of constraints being beneficial for superior functional performance in numerous shape memory alloys. However, process-induced ...
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Investigations on Tightness of Polymer-Metal Hybrids in Environments with Thermal, Media, and Mechanical Loads
(2017-07-31)
With polymer-metal hybrids becoming more commonly used as structural components it was investigated how they perform in complex environments with combined thermal, media, and mechanical loads. Special attention was put on media tightness under said loads. This paper sums up the activities of the polymer technology research group of the University of Kassel on hybrids produced by overmolding metal inserts. Investigations concerning joint strength and influence of (cyclic) temperature loads and chemical corrosion on ...
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Mechanical Properties of Polydimethylsiloxane as a Function of the Amount and Type of Crosslinking Agent
(2017-06-13)
In this investigation, a high-consistency rubber (HCR) was mixed with five different, typically used crosslinking agents that are based on organic peroxide. Furthermore, the amount of crosslinking agent was varied in order to quantify the effect on the mechanical properties. All materials were processed in a hot pressing process, and, subsequently, post-cured. The properties were characterized by the measurement of the swelling ratio, shore A-hardness, rebound resilience and tensile test. We successfully proved that ...
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Pathways towards grain boundary engineering for improved structural performance in polycrystalline Co-Ni-Ga shape memory alloys
(2018)
Co-Ni-Ga high-temperature shape memory alloys attracted a lot of scientific attention due to their superior functional material properties in recent years. In the single crystalline state Co-Ni-Ga HT-SMAs feature a good pseudoelastic response up to 500°C. However, in the polycrystalline condition Co-Ni-Ga suffers significant grain constraints and premature fracture at grain boundaries. In this regard, crystallographic orientation of the grain being involved as well as morphology and geometrical orientation of the ...
Aufsatz
Promoting abnormal grain growth in Fe-based shape memory alloys through compositional adjustments
(2019-05-28)
Iron-based shape memory alloys are promising candidates for large-scale structural applications due to their cost efficiency and the possibility of using conventional processing routes from the steel industry. However, recently developed alloy systems like Fe–Mn–Al–Ni suffer from low recoverability if the grains do not completely cover the sample cross-section. To overcome this issue, here we show that small amounts of titanium added to Fe–Mn–Al–Ni significantly enhance abnormal grain growth due to a considerable ...
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Cyclic degradation of Co49Ni21Ga30 high-temperature shape memory alloy - On the roles of dislocation activity and chemical order
(2015)
Conventional shape memory alloys (SMAs), such as binary Ni-Ti, are typically limited to service temperatures below 100 °C. Recent studies on Co-Ni-Ga high temperature (HT) SMAs revealed the potential that these alloys can be used up to temperatures of about 400 °C. Analysis of the cyclic functional properties showed that degradation in these alloys is mainly triggered by intensive dislocation motion. However, data on the cyclic stress-strain response and the mechanisms leading to functional degradation of Co-Ni-Ga ...
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Bend Straightening of a Carbonitrided Gear Shaft – Consequences on Residual Stresses and Retained Austenite near the Surface
(2017-06-20)
Carbonitriding of shafts in drive technology is strongly connected with distortion. Bend straightening is an important process step in order to eliminate distortion without removing the hardened surface layer. As shown in several investigations, even for simple part geometries, bending induced stresses and plastic deformations have a strong impact not only on the residual stress state but also on the microstructure after straightening. As gear shafts become increasingly filigree and complex in their geometry, the ...
Aufsatz
Climatic Ageing of Components of Polymer Based Electrochromic Devices
(2013-09-09)
Combining a shading function and a polycarbonate window displays an attractive alternative to the currently employed glass roof in vehicles. However, the ageing of such a device must be investigated before any application. Therefore, our investigations focus on the ageing of the components of a polycarbonate based electrochromic device. The optical, electrical, mechanical and electrochemical properties of the ion storage layer as well as the substrate will be assessed after storage in a climate with a high humidity ...
Aufsatz
Relaxation properties of polyoxymethylene and ethylene–octene copolymer blend in solid and melt states
(2012-08-30)
Rheological properties of polyoxymethylene (POM) and ethylene–octene copolymer (EOC) in solid and melt states were investigated. Blends were prepared with a twin screw extruder at broad component wt-to-wt ratios (10, 30, 50, 70, 90 wt% of EOC). The morphology as well as calorimetric, rheological, and elastic properties of the blends were studied. The investigation showed that POM/EOC blends were heterogeneous in nature and had a broad phase transition region between 30 and 70 wt% of POM. Because during processing ...