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Investigations on Tightness of Polymer-Metal Hybrids in Environments with Thermal, Media, and Mechanical Loads
(2017-07-31)
With polymer-metal hybrids becoming more commonly used as structural components it was investigated how they perform in complex environments with combined thermal, media, and mechanical loads. Special attention was put on media tightness under said loads. This paper sums up the activities of the polymer technology research group of the University of Kassel on hybrids produced by overmolding metal inserts. Investigations concerning joint strength and influence of (cyclic) temperature loads and chemical corrosion on ...
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Mechanical Properties of Polydimethylsiloxane as a Function of the Amount and Type of Crosslinking Agent
(2017-06-13)
In this investigation, a high-consistency rubber (HCR) was mixed with five different, typically used crosslinking agents that are based on organic peroxide. Furthermore, the amount of crosslinking agent was varied in order to quantify the effect on the mechanical properties. All materials were processed in a hot pressing process, and, subsequently, post-cured. The properties were characterized by the measurement of the swelling ratio, shore A-hardness, rebound resilience and tensile test. We successfully proved that ...
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Pathways towards grain boundary engineering for improved structural performance in polycrystalline Co-Ni-Ga shape memory alloys
(2018)
Co-Ni-Ga high-temperature shape memory alloys attracted a lot of scientific attention due to their superior functional material properties in recent years. In the single crystalline state Co-Ni-Ga HT-SMAs feature a good pseudoelastic response up to 500°C. However, in the polycrystalline condition Co-Ni-Ga suffers significant grain constraints and premature fracture at grain boundaries. In this regard, crystallographic orientation of the grain being involved as well as morphology and geometrical orientation of the ...
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Effect of nanometric γ´-particles on the stress-induced martensitic transformation in ⟨001⟩-oriented Co49Ni21Ga30 shape memory alloy single crystals
(2019)
The effect of finely dispersed particles on the functional properties and morphology of thermally induced martensite in Co-Ni-Ga shape memory alloys has been already reported in literature, however, still important aspects are not fully understood. The current study focuses on the stress-induced martensitic transformation of solution-annealed, i.e. precipitate-free, and aged 〈001〉-oriented single crystals. In situ optical microscopy and neutron diffraction experiments show a significant influence of γ′-particles on ...
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Wood-Polypropylene Composites: Influence of Processing on the Particle Shape and Size in Correlation with the Mechanical Properties Using Dynamic Image Analysis
(2018-11-16)
The particle size and shape are of momentous significance for the mechanical properties of plastic composites. However, natural fillers, like wood, are not consistent in these attributes. In order to investigate the shared traits between these characteristics, WPCs were produced using polypropylene, hardwood and softwood fillers with different particle sizes and a coupling agent. Afterwards, specimens were processed using an injection molding machine. The filler sizes and shapes were measured using dynamic image ...
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Cross-Linked Hydrophobic Starch Granules in Blends with PLA
(2018-04-17)
The majority of native starch is used in the food sector and in the paper industry. Only a small amount is used in polymer engineering. One reason for the reluctance of the plastics processing industry to use starch as a filling material in polymer blends is the unsatisfactory mechanical behavior of starch when combined with thermoplastics. Another reason is the hydrophilicity of starch. In order to make these materials capable of competing, an amelioration of the mechanical properties is compulsory. By means of ...