Relativistic effects in physics and chemistry of element 105. [Part] II.
| dc.date.accessioned | 2008-08-06T13:29:18Z | |
| dc.date.available | 2008-08-06T13:29:18Z | |
| dc.date.issued | 1992 | |
| dc.identifier.issn | 0021-9606 | |
| dc.identifier.uri | urn:nbn:de:hebis:34-2008080623127 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2008080623127 | |
| dc.format.extent | 705335 bytes | |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | American Institute of Physics | eng |
| dc.rights | Urheberrechtlich geschützt | |
| dc.rights.uri | https://rightsstatements.org/page/InC/1.0/ | |
| dc.subject.ddc | 530 | |
| dc.title | Relativistic effects in physics and chemistry of element 105. [Part] II. | eng |
| dc.type | Aufsatz | |
| dcterms.abstract | Relativistic self-consistent charge Dirac-Slater discrete variational method calculations have been done for the series of molecules MBr_5, where M = Nb, Ta, Pa, and element 105, Ha. The electronic structure data show that the trends within the group 5 pentabromides resemble those for the corresponding pentaclorides with the latter being more ionic. Estimation of the volatility of group 5 bromides has been done on the basis of the molecular orbital calculations. According to the results of the theoretical interpretation HaBr_5 seems to be more volatile than NbBr_5 and TaBr_5. | eng |
| dcterms.accessRights | open access | |
| dcterms.alternative | Electronic structure and properties of group 5 elements bromides | eng |
| dcterms.bibliographicCitation | In: Journal of chemical physics. Melvillle, NY : AIP. 97 (1992), Nr. 2, S. 1116-1122 | |
| dcterms.creator | Pershina, Valerija G. | |
| dcterms.creator | Sepp, Wolf-Dieter | |
| dcterms.creator | Fricke, Burkhard | |
| dcterms.creator | Kolb, Dietmar | |
| dcterms.creator | Schädel, M. | |
| dcterms.creator | Ionova, Galina V. |
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