Aufsatz
Relativistic prediction of the ground state of atomic Lawrencium
Abstract
In contradiction to the prediction of the Periodic Table but in agreement with earlier suggestions by Brewer and Mann, the ground state configuration of atomic Lawrencium (Z = 103) will not be 7s^2 6d^2 D_3/2 but 7s^2 7p ^2p_1/2. The reason for this deviation from normal trends across the Periodic Table are strong relativistic effects on the outermost 7P_l/2 orbital. Multicontiguration Dirac-Fock calculations are reported for Lawrencium and analogous lighter atoms. These calculations include contributions from magnetic and retardation interactions and an estimation of quantum electrodynamic corrections.
Citation
In: Journal de Physique. - Paris : Société Française de Physique, 41.1980, S. 943-946Citation
@article{urn:nbn:de:hebis:34-2008081923413,
author={Desclaux, Jean-Paul and Fricke, Burkhard},
title={Relativistic prediction of the ground state of atomic Lawrencium},
year={1980}
}
0500 Oax 0501 Text $btxt$2rdacontent 0502 Computermedien $bc$2rdacarrier 1100 1980$n1980 1500 1/eng 2050 ##0##urn:nbn:de:hebis:34-2008081923413 3000 Desclaux, Jean-Paul 3010 Fricke, Burkhard 4000 Relativistic prediction of the ground state of atomic Lawrencium / Desclaux, Jean-Paul 4030 4060 Online-Ressource 4085 ##0##=u http://nbn-resolving.de/urn:nbn:de:hebis:34-2008081923413=x R 4204 \$dAufsatz 4170 7136 ##0##urn:nbn:de:hebis:34-2008081923413
2008-08-19T08:56:42Z 2008-08-19T08:56:42Z 1980 0302-0738 0449-1947 urn:nbn:de:hebis:34-2008081923413 http://hdl.handle.net/123456789/2008081923413 387981 bytes application/pdf eng Urheberrechtlich geschützt https://rightsstatements.org/page/InC/1.0/ 530 Relativistic prediction of the ground state of atomic Lawrencium Aufsatz In contradiction to the prediction of the Periodic Table but in agreement with earlier suggestions by Brewer and Mann, the ground state configuration of atomic Lawrencium (Z = 103) will not be 7s^2 6d^2 D_3/2 but 7s^2 7p ^2p_1/2. The reason for this deviation from normal trends across the Periodic Table are strong relativistic effects on the outermost 7P_l/2 orbital. Multicontiguration Dirac-Fock calculations are reported for Lawrencium and analogous lighter atoms. These calculations include contributions from magnetic and retardation interactions and an estimation of quantum electrodynamic corrections. open access In: Journal de Physique. - Paris : Société Française de Physique, 41.1980, S. 943-946 Desclaux, Jean-Paul Fricke, Burkhard
The following license files are associated with this item:
Urheberrechtlich geschützt