Aufsatz
Theoretical study of the physicochemical properties of the light transactinides
Abstract
A theoretical study of the physicochemical properties of elements 104, 105, and 106 and their compounds in
the gas phase and aqueous solutions has been undertaken using relativistic atomic and molecular codes. Trends in properties such as bonding, ionization potentials, electron affinities, energies of electronic transitions, stabilities of oxidation states etc. have been defined within the corresponding chemical groups and within the transactinides.
These trends are shown to be determined by increasing relativistic effects within the groups. The behaviour of some gas phase compounds and complexes in solutions is predicted for the gas chromatography and solvent extraction experiments. Redox potentials in aqueous solutions of these elements are estimated.
the gas phase and aqueous solutions has been undertaken using relativistic atomic and molecular codes. Trends in properties such as bonding, ionization potentials, electron affinities, energies of electronic transitions, stabilities of oxidation states etc. have been defined within the corresponding chemical groups and within the transactinides.
These trends are shown to be determined by increasing relativistic effects within the groups. The behaviour of some gas phase compounds and complexes in solutions is predicted for the gas chromatography and solvent extraction experiments. Redox potentials in aqueous solutions of these elements are estimated.
Citation
@article{urn:nbn:de:hebis:34-2008100124229,
author={Pershina, Valerija G. and Fricke, Burkhard and Ionova, Galina V.},
title={Theoretical study of the physicochemical properties of the light transactinides},
year={1994}
}
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<resource xsi:schemaLocation="http://datacite.org/schema/kernel-2.2 http://schema.datacite.org/meta/kernel-2.2/metadata.xsd"> 2008-10-01T08:51:04Z 2008-10-01T08:51:04Z 1994 0925-8388 urn:nbn:de:hebis:34-2008100124229 http://hdl.handle.net/123456789/2008100124229 422265 bytes application/pdf eng Urheberrechtlich geschützt https://rightsstatements.org/page/InC/1.0/ 530 Theoretical study of the physicochemical properties of the light transactinides Aufsatz A theoretical study of the physicochemical properties of elements 104, 105, and 106 and their compounds in the gas phase and aqueous solutions has been undertaken using relativistic atomic and molecular codes. Trends in properties such as bonding, ionization potentials, electron affinities, energies of electronic transitions, stabilities of oxidation states etc. have been defined within the corresponding chemical groups and within the transactinides. These trends are shown to be determined by increasing relativistic effects within the groups. The behaviour of some gas phase compounds and complexes in solutions is predicted for the gas chromatography and solvent extraction experiments. Redox potentials in aqueous solutions of these elements are estimated. open access In: Journal of alloys and compounds. - Amsterdam [u.a.] : Elsevier, 213/214.1994, S. 33-37 Pershina, Valerija G. Fricke, Burkhard Ionova, Galina V. </resource>
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