The electronic structure of the group 6 oxyanions [MO_4]^2-, where M = Cr, Mo, W, and element 106
dc.date.accessioned | 2008-10-20T09:47:54Z | |
dc.date.available | 2008-10-20T09:47:54Z | |
dc.date.issued | 1994 | |
dc.identifier.issn | 0033-8230 | |
dc.identifier.uri | urn:nbn:de:hebis:34-2008102024591 | |
dc.identifier.uri | http://hdl.handle.net/123456789/2008102024591 | |
dc.format.extent | 482299 bytes | |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.rights | Urheberrechtlich geschützt | |
dc.rights.uri | https://rightsstatements.org/page/InC/1.0/ | |
dc.subject.ddc | 530 | |
dc.title | The electronic structure of the group 6 oxyanions [MO_4]^2-, where M = Cr, Mo, W, and element 106 | eng |
dc.type | Aufsatz | |
dcterms.abstract | The electronic structure of the group 6 oxyanions [MO_4]^2-, where M = Cr, Mo, W, and element 106 have been calculated using the Dirac-Slater Discrete Variational method. Results of the calculations show a relative decrease in the metal-oxygen bond strengths for the [E106O_4]^2- ion in the solid state compared to that for the [WO_4]^2- anion. Calculated energies of the electronic charge-transfer transitions are indicative of a strong possible luminescence of [El06O_4]^2- in the blue-violet area. In solutions [El06O_4]^2- will be the most stable ion out of the entire series. Estimated reduction potential E^0 (El06O^2-_4/E106O^3-_4) equal to -1.60V shows only a slightly increased stability of the +6 oxidation state for element 106 in comparison with W. | eng |
dcterms.accessRights | open access | |
dcterms.bibliographicCitation | In: Radiochimica acta. - Muenchen : Oldenbourg, 65.1994, S. 13-17 | |
dcterms.creator | Pershina, Valerija G. | |
dcterms.creator | Fricke, Burkhard |
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