Redox reactions of group 5 elements, including element 105, in aqueous solutions
| dc.date.accessioned | 2008-10-22T07:39:36Z | |
| dc.date.available | 2008-10-22T07:39:36Z | |
| dc.date.issued | 1992 | |
| dc.identifier.issn | 0022-3654 | |
| dc.identifier.issn | 0092-7325 | |
| dc.identifier.uri | urn:nbn:de:hebis:34-2008102224715 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2008102224715 | |
| dc.format.extent | 679440 bytes | |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.rights | Urheberrechtlich geschützt | |
| dc.rights.uri | https://rightsstatements.org/page/InC/1.0/ | |
| dc.subject.ddc | 530 | |
| dc.title | Redox reactions of group 5 elements, including element 105, in aqueous solutions | eng |
| dc.type | Aufsatz | |
| dcterms.abstract | Standard redox potentials E^0(M^z+x/M^z+) in acidic solutions for group 5 elements including element 105 (Ha) and the actinide, Pa, have been estimated on the basis of the ionization potentials calculated via the multiconfiguration Dirac-Fock method. Stability of the pentavalent state was shown to increase along the group from V to Ha, while that of the tetra- and trivalent states decreases in this direction. Our estimates have shown no extra stability of the trivalent state of hahnium. Element 105 should form mixed-valence complexes by analogy with Nb due to the similar values of their potentials E^0(M^3+/M^2+). The stability of the maximumoxidation state of the elements decreases in the direction 103 > 104 > 105. | eng |
| dcterms.accessRights | open access | |
| dcterms.bibliographicCitation | In: The Journal of Physical Chemistry. - Washington, DC : Soc.. - Easton, Pa., 96.1992, S. 11096 - 11101 | |
| dcterms.creator | Ionova, Galina V. | |
| dcterms.creator | Pershina, Valerija G. | |
| dcterms.creator | Johnson, Elijah | |
| dcterms.creator | Fricke, Burkhard | |
| dcterms.creator | Schädel, Matthias |
Dateien zu dieser Ressource
Das Dokument erscheint in:
-
Publikationen [132]