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Characterization of films and film-forming solutions of chitosan/thermoplastic rice starch associations: Role of starch oxidation and plasticizer type in the molecular interactions
(2023-09-29)
Polysaccharide films are alternative sources to replace fossil-based compounds. This study aimed to use rice starch modified by gelatinization and oxidation processes. Different properties were observed after blending it with chitosan and polyols, as evaluated on the film-forming solutions by rheology. The interaction between chitosan and oxidized starch appeared higher, as the plasticizers exhibited a low effect on the rheological behavior. Polyols played an essential role in chitosan/gelatinized associations, driven ...
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Mechanically induced dye-release from polyurea microcapsules in a rubbery adhesive
(2023-07-13)
Especially in the building industry the demand for in situ monitoring concepts of adhesive joints persists. In a new approach, microcapsules filled with special dyes, are added into a rubbery adhesive. Certain stress levels within the adhesive lead to a breakage of the capsules, which release their liquid cores. This results in a detectable colour change and thus, enables non-destructive condition monitoring of the bond. Dye-filled polyurea microcapsules were produced by interfacial polymerization by varying synthesis ...
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High Consistency Silicone Rubber Foams
(2024-04-23)
Silicone elastomers are high-performance plastics. In the extrusion process, only high-consistency silicone rubbers were used. In order to reduce the cost and weight, silicone rubbers can be foamed during processing. In this study, high-consistency silicone rubber is processed with different physical and chemical blowing agents. The resulting reaction kinetics, as well as the mechanical and morphological properties, had been investigated and compared with each other. This showed that the chemical blowing agent ...
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Electron beam powder bed fusion of Ti-30Ta high-temperature shape memory alloy: microstructure and phase transformation behaviour
(2024-06-19)
The present study reports on additive manufacturing of a Ti-30Ta (at.%) high-temperature shape memory alloy (HT-SMA) using electron beam powder bed fusion (PBF-EB/M) technique. Detailed microstructure analysis was conducted to reveal the microstructural evolution along the entire process chain, i.e. from gas-atomised powder to post-processed material. PBF-EB/M processed structures with near full density and an isotropic, β-phase stabilised microstructure, i.e. equiaxed β-grains of around 20 μm in diameter with no ...
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Susceptibility of a Fe-Mn-Al-Ni-Cr shape memory alloy to environment-assisted corrosion cracking
(2024-06-20)
In recent years, iron-based shape memory alloys (SMAs) have become increasingly interesting for application in civil engineering structures. Promising candidates in the field are iron-based Fe-Mn-Al-Ni-X (X = Ti, Cr) SMAs. These alloys have demonstrated the potential to be used in various types of applications. While the fully recoverable martensitic phase transformation can be used for structures where high damping capacities are required, i.e. for high rise buildings in earthquake prone areas, it has been successfully ...
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Fluorescence microscopic investigation of PCE superplasticiser adsorption in calcined clay blended cement
(2024-03-31)
Global efforts to minimise carbon dioxide emissions are also leading to attempts to use calcined clays (CC) as a partial substitute for cement in concrete. While the hydration mechanism of such CC blended cements is now well understood, the range of effective admixtures like polycarboxylate ethers (PCE) is limited. There are PCE types that promise relatively high effectiveness, but the mechanisms of action are not yet sufficiently understood. For a detailed understanding of the adsorption of such PCEs, spatially ...
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Correlation between the activation energy of PLA respectively PLA/starch composites and mechanical properties with regard to differ accelerated aging conditions
(2024-02-22)
Within this research semi-crystalline polylactide and composites with 50 wt.% native potato starch were compounded and injection molded. The material was mechanically characterized by tensile, three-point bending, and Charpy impact tests. These tests were carried out in the freshly molded state and after 332 and 792 h of storage at accelerated temperature or humidity. The respective activation energy was calculated by applying the Flynn-Wall-Ozawa method. The focus of the study was to investigate the correlation ...
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Influence of ethylene oxide and gamma irradiation sterilization processes on the degradation behaviour of poly(lactic acid) (PLA) in the course of artificially accelerated aging
(2024-02-10)
To promote the application of bio-based materials in the field of medical technology, it is essential to conduct additional research, focusing on their long-term performance after sterilization. For this purpose, the study examines the aging behaviour of three poly(lactic-acid) (PLA) materials, sterilized with either ethylene oxide or gamma irradiation, over a two years aging period, in accordance with ASTM F1980-21. During these investigations, a direct correlation between moisture absorption and degradation progression ...
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High-Speed Laser Cladding on Thin-Sheet-Substrates—Influence of Process Parameters on Clad Geometry and Dilution
(2021-08-09)
Laser-based Directed Energy Deposition (DED-LB) represents a production method of growing importance for cladding and additive manufacturing through the use of metal powders. Yet, most studies utilize substrate materials with thicknesses of multiple millimeters, for which laser cladding of thin-sheet substrates with thicknesses less than 1 mm have only been scarcely studied in the literature. Most studies cover the use of pulsed laser sources, since sheet distortion due to excess energy input is a key problem in laser ...
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Effect of Crystallographic Orientation and Grain Boundaries on Martensitic Transformation and Superelastic Response of Oligocrystalline Fe–Mn–Al–Ni Shape Memory Alloys
(2021-07-26)
In situ tensile tests employing digital image correlation were conducted to study the martensitic transformation of oligocrystalline Fe–Mn–Al–Ni shape memory alloys in depth. The influence of different grain orientations, i.e., near-〈001〉 and near-〈101〉, as well as the influence of different grain boundary misorientations are in focus of the present work. The results reveal that the reversibility of the martensite strongly depends on the type of martensitic evolving, i.e., twinned or detwinned. Furthermore, it is ...