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Date
2018-07-11
Author
Isenberg, StefanFrenzel, Lisa-MarieBruhn, ClemensPietschnig, Rudolf
Subject
540  Chemistry 
URI
urn:nbn:de:hebis:34-2018081756090

doi:10.3390/inorganics6030067
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Aufsatz

Metallated [3]Ferrocenophanes Containing P3M Bridges (M = Li, Na, K)

Abstract
Alkali-metal phosphanides can be embedded into a [3]ferrocenophane scaffold giving rise to bicyclic ferrocenophanes [MFe(C5H4PtBu)2P] (M = Li, Na, K). Coordination of the alkali-metal ions takes place via the terminal phosphorus atoms adopting a puckered P3M four-membered ring. All compounds were characterized via single-crystal X-ray diffraction and multinuclear NMR spectroscopy (1H, 31P, 7Li), whereas 13C NMR data could only be recorded for the Li derivative, owing to the limited solubility of its heavier congeners in unreactive solvents.
Citation
In: Inorganics. - Basel : MDPI. - 2018, 6(3), 67, 1-9
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Gefördert durch den Publikationsfonds der Universität Kassel
Collections
Publikationen  (Arbeitsgruppe Chemische Hybridmaterialien)
Artikel  (Publikationen im Open Access gefördert durch die UB)
Citation
@article{urn:nbn:de:hebis:34-2018081756090,
   author={Isenberg, Stefan and Frenzel, Lisa-Marie and Bruhn, Clemens and Pietschnig, Rudolf},
   title={Metallated [3]Ferrocenophanes Containing P3M Bridges (M = Li, Na, K)},
   year={2018}
}
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3010 Pietschnig, Rudolf
4000 Metallated [3]Ferrocenophanes Containing P3M Bridges (M = Li, Na, K) / Isenberg, Stefan
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2018-08-17T14:48:22Z
2018-08-17T14:48:22Z
2018-07-11
2304-6740
urn:nbn:de:hebis:34-2018081756090
http://hdl.handle.net/123456789/2018081756090
Gef&ouml;rdert durch den Publikationsfonds der Universit&auml;t Kassel
eng
Urheberrechtlich gesch&uuml;tzt
https://rightsstatements.org/page/InC/1.0/
alkali metal
phosphorus
ferrocenophane
phosphide
phosphanide
540
Metallated [3]Ferrocenophanes Containing P3M Bridges (M = Li, Na, K)
Aufsatz
Alkali-metal phosphanides can be embedded into a [3]ferrocenophane scaffold giving rise to bicyclic ferrocenophanes [MFe(C5H4PtBu)2P] (M = Li, Na, K). Coordination of the alkali-metal ions takes place via the terminal phosphorus atoms adopting a puckered P3M four-membered ring. All compounds were characterized via single-crystal X-ray diffraction and multinuclear NMR spectroscopy (1H, 31P, 7Li), whereas 13C NMR data could only be recorded for the Li derivative, owing to the limited solubility of its heavier congeners in unreactive solvents.
open access
In: Inorganics. - Basel : MDPI. - 2018, 6(3), 67, 1-9
Isenberg, Stefan
Frenzel, Lisa-Marie
Bruhn, Clemens
Pietschnig, Rudolf
doi:10.3390/inorganics6030067
</resource>

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Urheberrechtlich geschützt