High-resolution infrared spectra and rovibrational analysis of the v12 band of propylene oxide
| dc.date.accessioned | 2024-11-04T06:53:15Z | |
| dc.date.available | 2024-11-04T06:53:15Z | |
| dc.date.issued | 2024-08-27 | |
| dc.description.sponsorship | Gefördert im Rahmen des Projekts DEAL | |
| dc.identifier | doi:10.17170/kobra-2024110111050 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/16132 | |
| dc.language.iso | eng | |
| dc.relation.doi | doi:10.1039/d4cp02943g | |
| dc.rights | Namensnennung 4.0 International | * |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | * |
| dc.subject.ddc | 530 | |
| dc.subject.ddc | 540 | |
| dc.subject.ddc | 620 | |
| dc.subject.swd | Infrarotspektroskopie | ger |
| dc.subject.swd | Vibrationsananlyse | ger |
| dc.subject.swd | Propylenoxid | ger |
| dc.title | High-resolution infrared spectra and rovibrational analysis of the v12 band of propylene oxide | eng |
| dc.type | Aufsatz | |
| dc.type.version | publishedVersion | |
| dcterms.abstract | The high-resolution infrared spectrum of the fundamental band ν12 (ring breathing) of the chiral molecule propylene oxide (CH3CHCH2O) was recorded at room temperature and under jet-cooled conditions using a quantum cascade laser at 8 μm. The observed lines with quantum numbers J ≤ 55 and Ka ≤ 21 were assigned to strong b- and c-type bands{,} and some low J transitions were classified as weak a-type transitions. The lines were fitted using a Watsons A-reduced Hamiltonian in the Ir representation. From the rovibrational analysis the band origin as well as the rotational constants and four quartic centrifugal distortion constants were derived. | eng |
| dcterms.accessRights | open access | |
| dcterms.creator | Vávra, Karel | |
| dcterms.creator | Döring, Eileen | |
| dcterms.creator | Jakob, Jan | |
| dcterms.creator | Peterß, Fabian | |
| dcterms.creator | Kaufmann, Matin | |
| dcterms.creator | Stahl, Pascal | |
| dcterms.creator | Giesen, Thomas F. | |
| dcterms.creator | Fuchs, Guido W. | |
| dcterms.source.identifier | eissn:1463-9076 | |
| dcterms.source.issue | Issue 36 | |
| dcterms.source.journal | Physical Chemistry, Chemical Physics (PCCP) | eng |
| dcterms.source.pageinfo | 23886 - 23892 | |
| dcterms.source.volume | Volume 26 | |
| kup.iskup | false |