Reduction Behavior of Anisyl-substituted P-Ferrocenyl Phospholes

Simple item page
dc.date.accessioned2023-07-26T06:53:51Z
dc.date.available2023-07-26T06:53:51Z
dc.date.issued2023-05-26
dc.description.sponsorshipGefördert im Rahmen des Projekts DEAL
dc.identifierdoi:10.17170/kobra-202307268478
dc.identifier.urihttp://hdl.handle.net/123456789/14926
dc.language.isoeng
dc.relation.doidoi:10.1002/cplu.202300143
dc.rightsNamensnennung 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectelectrochemistryeng
dc.subjectferroceneeng
dc.subjectheterocycleeng
dc.subjectphosphoruseng
dc.subjectreductioneng
dc.subject.ddc540
dc.subject.swdElektrochemieger
dc.subject.swdFerrocenger
dc.subject.swdPhosphorger
dc.subject.swdReduktion <Chemie>ger
dc.titleReduction Behavior of Anisyl-substituted P-Ferrocenyl Phospholeseng
dc.typeAufsatz
dc.type.versionpublishedVersion
dcterms.abstractP-Ferrocenylphospholes with differing substituents in α-position have been synthesized and their identity and purity was confirmed using multinuclear NMR spectroscopy, MS, elemental analysis and single crystal X-ray diffraction. Furthermore, the redox properties have been explored with electrochemical measurements. Transferring the reduction to a preparative scale using lithium leads to reductive P−C bond cleavage furnishing the corresponding phospholide which has been transformed to P-tert-butyl substituted phosphole. In addition to phospholide formation reductive demethoxylation with transformation of the anisyl substituent to its phenyl analog was observed. For comparison analogous reactions have been explored for the respective P-phenylphospholes which show a different reactivity.eng
dcterms.accessRightsopen access
dcterms.creatorGetfert, Katharina
dcterms.creatorRoesler, Fabian
dcterms.creatorBruhn, Clemens
dcterms.creatorPietschnig, Rudolf
dcterms.extent8 Seiten
dcterms.source.identifiereissn:2192-6506
dcterms.source.issueIssue 6
dcterms.source.journalChemPlusChemeng
dcterms.source.volumeVolume 88
kup.iskupfalse

Files

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
ChemPlusChem_2023_Getfert_Reduction_Behavior_of_Anisyl_substituted_P_Ferrocenyl_Phospholes.pdf
Size:
2.05 MB
Format:
Adobe Portable Document Format
Description:
Download

License bundle

Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
3.03 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

Artikel