🇬🇧

Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes

Roesler, Fabian
Bruhn, Clemens
Pietschnig, Rudolf

A series of coinage metal complexes asymmetrically substituted 2,5-diaryl phosphole ligands is reported. Structure, identity, and purity of all obtained complexes were corroborated with state-of-the-art techniques (multinuclear NMR, mass spectrometry, elemental analysis, X-ray diffraction) in solution and solid state. All complexes obtained feature luminescence in solution as well as in the solid state. Additionally, DOSY-MW NMR estimation experiments were performed to achieve information about the aggregation behavior of the complexes in solution allowing a direct comparison with their structures observed in the solid state.

Sponsor
Gefördert durch den Publikationsfonds der Universität Kassel
Citation
In: Molecules Volume 27 / Issue 11 (2022-05-24) , S. ; eissn:1420-3049
Collections
@article{doi:10.17170/kobra-202208196705,
  author    ={Roesler, Fabian and Bruhn, Clemens and Pietschnig, Rudolf},
  title    ={Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes},
  keywords ={540 and Phosphororganische Verbindungen and Lumineszenz and Münzmetall and Koordinationslehre and Chiralität },
  copyright  ={http://creativecommons.org/licenses/by/4.0/},
  language ={en},
  journal  ={Molecules},
  year   ={2022-05-24}
}