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Fabrication and characterization of ethylene–octene copolymer composites with ionic liquid functionalized carbon nanotubes

Modification of multi-walled carbon nanotubes (MWCNTs) by means of imidazolium ionic liquid (IL) was performed. Structural characterization of funtionalized nanofillers (IL-f-MWCNTs) was made by means of Raman spectroscopy and transmission electron microscopy. MWCNTs and IL-f-MWCNTs were introduced within ethylene octane copolymer (EOC) with octene co-monomer content of 17% by using the masterbatch approach. The efficiency of the carbonaceous nanofiller distribution within the polymer matrix was characterized by means of scanning electron microscopy. It was shown that MWCNTs and IL-f-MWCNTs were both effective in rising storage modulus, tensile modulus, stress-at break, and electrical conductivity of EOC-based nanocomposites along with the increasing nanofiller content. Besides, it was observed that the modification efficiency of the investigated EOC matrix composites by IL-f-MWCNTs was greater in comparison to pristine MWCNTs.

Citation
In: Proceedings of the Estonian Academy of Sciences Volume 66 / Issue 4 (2017-10-16) , S. 347-353; EISSN 1736-7530
Collections
@article{doi:10.17170/kobra-202012082425,
  author    ={Meri, Remo Merijs and Zicans, Janis and Ivanova, Tatjana and Saldabola, Ruta and Reinholds, Ingars and Roja, Zhenija and Feldmann, Maik Wilhelm and Heim, Hans-Peter},
  title    ={Fabrication and characterization of ethylene–octene copolymer composites with ionic liquid functionalized carbon nanotubes},
  keywords ={540 and 600 and Werkstoffkunde and Kohlenstoff-Nanoröhre and Polyethylene and Copolymere and Nanokomposit},
  copyright  ={http://creativecommons.org/licenses/by-nc/4.0/},
  language ={en},
  journal  ={Proceedings of the Estonian Academy of Sciences},
  year   ={2017-10-16}
}