Chalcogen‐Transfer Rearrangement: Exploring Inter‐ versus Intramolecular P−P Bond Activation

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dc.date.accessioned2021-01-22T11:08:00Z
dc.date.available2021-01-22T11:08:00Z
dc.date.issued2020-07-17
dc.description.sponsorshipGefördert im Rahmen des Projekts DEALger
dc.identifierdoi:10.17170/kobra-202101213012
dc.identifier.urihttp://hdl.handle.net/123456789/12433
dc.language.isoengeng
dc.relation.doidoi:10.1002/chem.202002481
dc.rightsNamensnennung 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectbond activationeng
dc.subjectchalcogenseng
dc.subjectferroceneseng
dc.subjectmultinuclear NMR spectroscopyeng
dc.subjectphosphoruseng
dc.subject.ddc540
dc.subject.swdChemische Bindungger
dc.subject.swdAktivierung <Chemie>ger
dc.subject.swdChalkogeneger
dc.subject.swdFerrocenger
dc.subject.swdNMR-Spektroskopieger
dc.subject.swdPhosphorger
dc.titleChalcogen‐Transfer Rearrangement: Exploring Inter‐ versus Intramolecular P−P Bond Activationeng
dc.typeAufsatz
dc.type.versionpublishedVersion
dcterms.abstracttert‐Butyl‐substituted diphospha[2]ferrocenophane has been used as a stereochemically confined diphosphane to explore the addition of O, S, Se and Te. Although the diphosphanylchalcogane has been obtained for tellurium, all other chalcogens give diphosphane monochalcogenides. The latter transform via chalcogen‐transfer rearrangement to the corresponding diphosphanylchalcoganes upon heating. The kinetics of this rearrangement has been followed with NMR spectroscopy supported by DFT calculations. Intermediates during rearrangement point to a disproportionation/synproportionation mechanism for the S and Se derivatives. Cyclic voltammetry together with DFT studies indicate ferrocene‐centred oxidation for most of the compounds presented.eng
dcterms.accessRightsopen access
dcterms.creatorFranz, Roman
dcterms.creatorNasemann, Sina
dcterms.creatorBruhn, Clemens
dcterms.creatorKelemen, Zsolt
dcterms.creatorPietschnig, Rudolf
dcterms.source.identifierEISSN 1521-3765
dcterms.source.issueIssue 2
dcterms.source.journalChemistryeng
dcterms.source.pageinfo641-648
dcterms.source.volumeVolume 27
kup.iskupfalse

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