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Preparation and Molecular Structure of a Cyclopentyl-Substituted Cage Hexasilsesquioxane T6 (T = cyclopentyl-SiO1.5) Starting from the Corresponding Silanetriol

Kahr, Jürgen
Belaj, Ferdinand
Pietschnig, Rudolf

Cyclopentyl substituted silanetriol can be prepared and isolated. Its condensation yields the corresponding disiloxanetetrol as a primary condensation product. Further condensation leads to the hexameric polyhedral silsesquioxane cage T6. The latter has been mentioned in the literature before however, lacking structural data. All compounds have been characterized with multinuclear NMR spectroscopy and, in addition, the molecular structures have been determined in the case of the disiloxanetetrol and the hexasilsesquioxane via single crystal X-ray diffraction.

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Gefördert durch den Publikationsfonds der Universität Kassel 
@article{urn:nbn:de:hebis:34-2018020254389,
  author    ={Kahr, Jürgen and Belaj, Ferdinand and Pietschnig, Rudolf},
  title    ={Preparation and Molecular Structure of a Cyclopentyl-Substituted Cage Hexasilsesquioxane T6 (T = cyclopentyl-SiO1.5) Starting from the Corresponding Silanetriol},
  copyright  ={https://rightsstatements.org/page/InC/1.0/},
  language ={en},
  year   ={2017-10-04}
}