Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation
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In: ChemistryOpen Volume 8 / Issue 10 (2019-06-26) , S. 1235-1243; ISSN 2191-1363
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A series of bis‐[3]ferrocenophanes of the general type Fe(C5H4E’)2E−E(E'C5H4)2Fe (E=P, SiH and E’=PtBu, NneoPentyl, NSi(CH3)3) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X‐ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.
@article{doi:10.17170/kobra-20191213869,
author ={Isenberg, Stefan and Weller, Stefan and Kargin, Denis and Valić, Srećko and Schwederski, Brigitte and Kelemen, Zsolt and Bruhn, Clemens and Krekić, Kristijan and Maurer, Martin and Feil, Christoph M. and Nieger, Martin and Gudat, Dietrich and Nyulászi, László and Pietschnig, Rudolf},
title ={Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation},
copyright ={https://rightsstatements.org/page/InC/1.0/},
language ={en},
journal ={ChemistryOpen},
year ={2019-06-26}
}