Oxidation Reactions of the N-Heterocyclic Stannylenes [š°-CāHā (NSiš”BuMeā)]āSn and [{Fe(Ī·āµ -Cā Hā -NSiš”BuMeā)ā}Sn] with Sulfur, Selenium, and Diphenyl Diselenide
| dc.date.accessioned | 2020-07-20T08:11:37Z | |
| dc.date.available | 2020-07-20T08:11:37Z | |
| dc.date.issued | 2020-01-27 | |
| dc.identifier | doi:10.17170/kobra-202007171462 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/11647 | |
| dc.language.iso | eng | eng |
| dc.relation.doi | doi:10.1002/zaac.201900335 | |
| dc.rights | Namensnennung 4.0 International | * |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | * |
| dc.subject | Carbene homologues | eng |
| dc.subject | Metallocenes | eng |
| dc.subject | Oxidative addition | eng |
| dc.subject | Tin | eng |
| dc.subject | X-ray diffraction | eng |
| dc.subject.ddc | 540 | |
| dc.subject.swd | Carbene | ger |
| dc.subject.swd | Homologe <Chemie> | ger |
| dc.subject.swd | Rƶntgendiffraktometrie | ger |
| dc.title | Oxidation Reactions of the N-Heterocyclic Stannylenes [š°-CāHā (NSiš”BuMeā)]āSn and [{Fe(Ī·āµ -Cā Hā -NSiš”BuMeā)ā}Sn] with Sulfur, Selenium, and Diphenyl Diselenide | eng |
| dc.type | Aufsatz | |
| dc.type.version | publishedVersion | |
| dcterms.abstract | The Nāheterocyclic stannylenes [{Fe(Ī·$^5$āC$_5$H$_4$āNSiš” BuMe$_2$)$_2$}Sn] (1 ) and [š°āC$_6$H$_4$(NSiš” BuMe$_2$)]$_2$Sn (2 ) were prepared in oneāpot reactions from SnCl$_2$, LiN(SiMe$_3$)$_2$, and the corresponding diamine, viz. [Fe(Ī·$^5$āC$_5$H$_4$āNHSiš” BuMe$_2$)$_2$] and š°āC$_6$H$_4$(NSiHšµ BuMe$_2$)$_2$, respectively. Oxidative addition reactions of 1 and 2 with S$_8$ and Se$_8$, respectively, afforded the corresponding 1,3,2,4ādithiadistannetanes ((1 S$_2$), (2 S$_2$)), and 1,3,2,4ādiselenadistannetanes [(1 Se)$_2$, (2 Se)$_2$]. The reactions of 1 and 2 with PhSeSePh respectively furnished 1 (SePh)$_2$ and 2 (SePh)$_2$. The crystal structures of š°āC$_6$H$_4$(NSiHš” BuMe$_2$)$_2$, 1, 2, ( 1 S)$_2$, (2 S)$_2$, (1 Se)$_2$, (2 Se)$_2$, 1 (SePh)$_2$, and 2 (SePh)$_2$ were determined by singleācrystal Xāray diffraction. Stannylene 2 shows a chainālike aggregation in the solid state due to intermolecular SnāÆarene interactions. A short intramolecular CHāÆSe contact compatible with a hydrogen bond was observed for (1 Se)$_2$. | eng |
| dcterms.accessRights | open access | |
| dcterms.creator | Guthardt, Robin | |
| dcterms.creator | Bachmann, Dennis | |
| dcterms.creator | Bruhn, Clemens | |
| dcterms.creator | Siemeling, Ulrich | |
| dcterms.source.identifier | EISSN 1521-3749 | |
| dcterms.source.issue | Issue 13 | |
| dcterms.source.journal | Journal of Inorganic and General Chemistry : ZAAC | eng |
| dcterms.source.pageinfo | 761-768 | |
| dcterms.source.volume | Volume 646 | |
| kup.iskup | false |