High-resolution absorption, dispersed fluorescence emission, and photoionization cross sections are presented for gas-phase adamantane excited by synchrotron radiation in the exciting-photon energy range of 6–30 eV. Relative and absolute absorption cross sections of so-far unmatched resolution of down to 0.27 cm−¹ line width in the region from 6.4–28 eV are shown along with newly discovered vibronic substructures around the HOMO–LUMO transition. Absorption line positions are provided with very high accuracy and listed in tabular form to be used as spectral fingerprints for the detection of adamantane in interstellar media, where its column density may be determined via the absolute cross sections. The fluorescence emission lies in the ultraviolet range from 190–250 nm and is excited starting at the HOMO–LUMO transition at 6.49 eV, which corresponds to the highest fluorescence emission energy. Hitherto unreported fluorescence in the same spectral range and relative photoionization cross sections in the exciting-photon energy range up to 30 eV are also presented along with lifetime measurements for differentiation of the involved electronic states.
@article{doi:10.17170/kobra-202309118758,
author ={Marder, Lutz and Breier, Alexander Axel and Oliveira, Nelson de and Reiß, Philipp and Ozga, Christian and Küstner-Wetekam, Catmarna and Giesen, Thomas and Nahon, Laurent and Hans, Andreas and Knie, André and Ehresmann, Arno and Schmidt, Philipp},
title ={Vibrationally Resolved Absorption and Fluorescence Cross Sections of Adamantane in the Far-ultraviolet Spectral Range on an Absolute Scale},
keywords ={530 and 620 and Ultraviolettspektroskopie and Molekülspektroskopie and Fotoionisation and Interstellares Molekül and Fluoreszenz and Absorption},
copyright ={http://creativecommons.org/licenses/by/4.0/},
language ={en},
journal ={The Astrophysical Journal Supplement},
year ={2023-07-20}
}