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2022-05-24Subject
540 Chemistry Phosphororganische VerbindungenLumineszenzMünzmetallKoordinationslehreChiralität <Chemie>Metadata
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Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes
Abstract
A series of coinage metal complexes asymmetrically substituted 2,5-diaryl phosphole ligands is reported. Structure, identity, and purity of all obtained complexes were corroborated with state-of-the-art techniques (multinuclear NMR, mass spectrometry, elemental analysis, X-ray diffraction) in solution and solid state. All complexes obtained feature luminescence in solution as well as in the solid state. Additionally, DOSY-MW NMR estimation experiments were performed to achieve information about the aggregation behavior of the complexes in solution allowing a direct comparison with their structures observed in the solid state.
Citation
In: Molecules Volume 27 / Issue 11 (2022-05-24) eissn:1420-3049Sponsorship
Gefördert durch den Publikationsfonds der Universität KasselCitation
@article{doi:10.17170/kobra-202208196705,
author={Roesler, Fabian and Bruhn, Clemens and Pietschnig, Rudolf},
title={Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes},
journal={Molecules},
year={2022}
}
0500 Oax 0501 Text $btxt$2rdacontent 0502 Computermedien $bc$2rdacarrier 1100 2022$n2022 1500 1/eng 2050 ##0##http://hdl.handle.net/123456789/14090 3000 Roesler, Fabian 3010 Bruhn, Clemens 3010 Pietschnig, Rudolf 4000 Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes / Roesler, Fabian 4030 4060 Online-Ressource 4085 ##0##=u http://nbn-resolving.de/http://hdl.handle.net/123456789/14090=x R 4204 \$dAufsatz 4170 5550 {{Phosphororganische Verbindungen}} 5550 {{Lumineszenz}} 5550 {{Münzmetall}} 5550 {{Koordinationslehre}} 5550 {{Chiralität <Chemie>}} 7136 ##0##http://hdl.handle.net/123456789/14090
2022-08-22T14:01:57Z 2022-08-22T14:01:57Z 2022-05-24 doi:10.17170/kobra-202208196705 http://hdl.handle.net/123456789/14090 Gefördert durch den Publikationsfonds der Universität Kassel eng Namensnennung 4.0 International http://creativecommons.org/licenses/by/4.0/ organophosphorus chemistry luminescence coinage metal coordination chemistry chirality 540 Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes Aufsatz A series of coinage metal complexes asymmetrically substituted 2,5-diaryl phosphole ligands is reported. Structure, identity, and purity of all obtained complexes were corroborated with state-of-the-art techniques (multinuclear NMR, mass spectrometry, elemental analysis, X-ray diffraction) in solution and solid state. All complexes obtained feature luminescence in solution as well as in the solid state. Additionally, DOSY-MW NMR estimation experiments were performed to achieve information about the aggregation behavior of the complexes in solution allowing a direct comparison with their structures observed in the solid state. open access Roesler, Fabian Bruhn, Clemens Pietschnig, Rudolf doi:10.3390/molecules27113368 Phosphororganische Verbindungen Lumineszenz Münzmetall Koordinationslehre Chiralität <Chemie> publishedVersion eissn:1420-3049 Issue 11 Molecules Volume 27 false 3368
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