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Aufsatz
Climatic Ageing of Components of Polymer Based Electrochromic Devices
(2013-09-09)
Combining a shading function and a polycarbonate window displays an attractive alternative to the currently employed glass roof in vehicles. However, the ageing of such a device must be investigated before any application. Therefore, our investigations focus on the ageing of the components of a polycarbonate based electrochromic device. The optical, electrical, mechanical and electrochemical properties of the ion storage layer as well as the substrate will be assessed after storage in a climate with a high humidity ...
Aufsatz
UV Surface Treatment of Polycarbonate for Adhesion Improvement to Liquid Silicone Rubber (LSR)
(2018)
The adhesion of self-adhesive liquid silicone rubbers to thermoplasts is only possible for a few selected material combinations without a surface pretreatment. A UV pretreatment is effective for polycarbonate and short irradiation periods are sufficient. To clarify the required irradiation conditions that result in an improvement of adhesion, the varying irradiation conditions were assessed. FTIR-ATR spectroscopy was used for surface analysis to characterize the change in the polymer surface.
Aufsatz
Spatio-temporal resolution studies on a highly compact ultrafast electron diffractometer
(2015)
Time-resolved diffraction with femtosecond electron pulses has become a promising technique to directly provide insights into photo induced primary dynamics at the atomic level in molecules and solids. Ultrashort pulse duration as well as extensive spatial coherence are desired, however, space charge effects complicate the bunching of multiple electrons in a single pulse.Weexperimentally investigate the interplay between spatial and temporal aspects of resolution limits in ultrafast electron diffraction (UED) on our ...
Aufsatz
Characterization of wood-based multi-material systems under dynamic impact stress
(2018)
Due to its naturally grown properties, wood has played a rather subordinate role as a material for technical applications up to now. In this paper, multi-material systems based on veneers of beech (Fagus sylvatica) with different reinforcing variants were investigated. In addition to the influence of different adhesive systems (urea formaldehyde and polyurethane), the effect of reinforcing by aramid fiber fabric and stainless steel foil in different climates was examined. At the center of the investigations were ...
Aufsatz
Cross-Linked Hydrophobic Starch Granules in Blends with PLA
(2018-04-17)
The majority of native starch is used in the food sector and in the paper industry. Only a small amount is used in polymer engineering. One reason for the reluctance of the plastics processing industry to use starch as a filling material in polymer blends is the unsatisfactory mechanical behavior of starch when combined with thermoplastics. Another reason is the hydrophilicity of starch. In order to make these materials capable of competing, an amelioration of the mechanical properties is compulsory. By means of ...
Aufsatz
Investigations on Tightness of Polymer-Metal Hybrids in Environments with Thermal, Media, and Mechanical Loads
(2017-07-31)
With polymer-metal hybrids becoming more commonly used as structural components it was investigated how they perform in complex environments with combined thermal, media, and mechanical loads. Special attention was put on media tightness under said loads. This paper sums up the activities of the polymer technology research group of the University of Kassel on hybrids produced by overmolding metal inserts. Investigations concerning joint strength and influence of (cyclic) temperature loads and chemical corrosion on ...
Aufsatz
Mechanical Properties of Polydimethylsiloxane as a Function of the Amount and Type of Crosslinking Agent
(2017-06-13)
In this investigation, a high-consistency rubber (HCR) was mixed with five different, typically used crosslinking agents that are based on organic peroxide. Furthermore, the amount of crosslinking agent was varied in order to quantify the effect on the mechanical properties. All materials were processed in a hot pressing process, and, subsequently, post-cured. The properties were characterized by the measurement of the swelling ratio, shore A-hardness, rebound resilience and tensile test. We successfully proved that ...
Aufsatz
Wood-Polypropylene Composites: Influence of Processing on the Particle Shape and Size in Correlation with the Mechanical Properties Using Dynamic Image Analysis
(2018-11-16)
The particle size and shape are of momentous significance for the mechanical properties of plastic composites. However, natural fillers, like wood, are not consistent in these attributes. In order to investigate the shared traits between these characteristics, WPCs were produced using polypropylene, hardwood and softwood fillers with different particle sizes and a coupling agent. Afterwards, specimens were processed using an injection molding machine. The filler sizes and shapes were measured using dynamic image ...
Aufsatz
Additive manufacturing of Co-Ni-Ga high-temperature shape memory alloy - Processability 3 and phase transformation behavior
(2019)
Co-Ni-Ga high-temperature shape memory alloy is additively processed by selective laser melting for the first time. Reversiblemartensitic transformation of the as-built material is proven by differential scanning calorimetry. Microstructural analysis reveals a columnar-grained microstructure due to epitaxial solidification. Columnar-grained microstructures are characterized by a very low degree of constraints being beneficial for superior functional performance in numerous shape memory alloys. However, process-induced ...
Aufsatz
Pathways towards grain boundary engineering for improved structural performance in polycrystalline Co-Ni-Ga shape memory alloys
(2018)
Co-Ni-Ga high-temperature shape memory alloys attracted a lot of scientific attention due to their superior functional material properties in recent years. In the single crystalline state Co-Ni-Ga HT-SMAs feature a good pseudoelastic response up to 500°C. However, in the polycrystalline condition Co-Ni-Ga suffers significant grain constraints and premature fracture at grain boundaries. In this regard, crystallographic orientation of the grain being involved as well as morphology and geometrical orientation of the ...