Datum
2020-01-10Schlagwort
600 Technik UmweltbelastungGrenzflächenspannungOberflächenspannungStoffeigenschaftMaterialbearbeitungKristallstrukturBiologisch abbaubarer KunststoffMetadata
Zur Langanzeige
Aufsatz
Influence of the degree of crystallinity and the surface free energy on the adhesion properties of different PLA/PBS blends in multicomponent injection molding
Zusammenfassung
Biocomposites made of biodegradable polymers have grown in interest due to their environmentally friendliness, considering that non-biodegradable polymers waste conduces to pollution, displaying high environmental impact in climatic changes. Therefore, in the presented study, biodegradable Poly (lactic acid) (PLA) and poly (butylene succinate) (PBS) were investigated as a series of PLA/PBS melt-blending compounds with the weight ratios of 50/50, 60/40, 70/30, 80/20 and 90/10. In a two-component injection molding process, they were used as the hard component to create hard-soft- combinations. Thermal properties, crystallinity and mechanical properties were examined with regard to the change in the adhesive bonding strength between the PLA/PBS compounds and thermoplastic polyurethane (TPU) under the influence of time and temperature (storage at room temperature and 100 °C in the course of 1, 3, 7 and 14 day(s)). The adhesion properties of the PLA/PBS blends were identified via Drop Shape Analysis (DSA) using a contact angle measurement device and corroborated with FTIR/ATR measurements. The attenuation in the interfacial tension between the blends and TPU with increasing amount of PBS content in the blend provided better bonding abilities. The maximal load required to disconnect these two components was measured by a universal tensile test machine. According to the results, the highest maximal load (552,69 N) was achieved with the PLA/PBS blend with a weight ratio of 60/40 wt% after being subjected to seven days of storage at 100 °C.
Zitierform
In: AIP Conference Proceedings Volume 2205 / Issue 1 (2020-01-10) , S. 020019-1 - 020019-5 ; eissn:1551-7616Zusätzliche Informationen
This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in AIP Conference Proceedings 2205, 020019 (2020) and may be found at https://doi.org/10.1063/1.5142934.Zitieren
@article{doi:10.17170/kobra-202012012320,
author={Güzel, Kübra and Klute, Marco and Kurgan, Naci and Heim, Hans-Peter},
title={Influence of the degree of crystallinity and the surface free energy on the adhesion properties of different PLA/PBS blends in multicomponent injection molding},
journal={AIP Conference Proceedings},
year={2020}
}
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2020-12-04T16:13:21Z 2020-12-04T16:13:21Z 2020-01-10 doi:10.17170/kobra-202012012320 http://hdl.handle.net/123456789/12095 This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in AIP Conference Proceedings 2205, 020019 (2020) and may be found at https://doi.org/10.1063/1.5142934. eng Urheberrechtlich geschützt https://rightsstatements.org/page/InC/1.0/ environmental impacts mechanical instruments interfacial tension surface energy material properties material synthesis and processing crystal structure adhesive bonding polymers 600 Influence of the degree of crystallinity and the surface free energy on the adhesion properties of different PLA/PBS blends in multicomponent injection molding Aufsatz Biocomposites made of biodegradable polymers have grown in interest due to their environmentally friendliness, considering that non-biodegradable polymers waste conduces to pollution, displaying high environmental impact in climatic changes. Therefore, in the presented study, biodegradable Poly (lactic acid) (PLA) and poly (butylene succinate) (PBS) were investigated as a series of PLA/PBS melt-blending compounds with the weight ratios of 50/50, 60/40, 70/30, 80/20 and 90/10. In a two-component injection molding process, they were used as the hard component to create hard-soft- combinations. Thermal properties, crystallinity and mechanical properties were examined with regard to the change in the adhesive bonding strength between the PLA/PBS compounds and thermoplastic polyurethane (TPU) under the influence of time and temperature (storage at room temperature and 100 °C in the course of 1, 3, 7 and 14 day(s)). The adhesion properties of the PLA/PBS blends were identified via Drop Shape Analysis (DSA) using a contact angle measurement device and corroborated with FTIR/ATR measurements. The attenuation in the interfacial tension between the blends and TPU with increasing amount of PBS content in the blend provided better bonding abilities. The maximal load required to disconnect these two components was measured by a universal tensile test machine. According to the results, the highest maximal load (552,69 N) was achieved with the PLA/PBS blend with a weight ratio of 60/40 wt% after being subjected to seven days of storage at 100 °C. open access Güzel, Kübra Klute, Marco Kurgan, Naci Heim, Hans-Peter doi:10.1063/1.5142934 Umweltbelastung Grenzflächenspannung Oberflächenspannung Stoffeigenschaft Materialbearbeitung Kristallstruktur Biologisch abbaubarer Kunststoff publishedVersion eissn:1551-7616 Issue 1 AIP Conference Proceedings 020019-1 - 020019-5 Volume 2205 false
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