Datum
2023-12-13Autor
Nasemann, SinaFranz, RomanKargin, DenisBruhn, ClemensKelemen, ZsoltGutmann, TorstenPietschnig, RudolfMetadata
Zur Langanzeige
Aufsatz
German Science Fund (DFG) for financial support (CRC 1319 ELCH); János Bolyai Research Scholarship and Project UNKP-23-5 BME-419
At the limits of bisphosphonio-substituted stannylenes
Zusammenfassung
Donor stabilization of Sn(II) and Pb(II) halides with 1,1’-ferrocenylene bridged bisphosphanes has been explored for Fe(C₅H₄P(C6H₅)₂)₂ (dppf), and Fe(C₅H₄PH(C₄H9))₂. These bisphosphanes are reacted with SnBr₂ and PbCl₂ with and without additional Lewis acid (AlCl₃) forming acyclic and cyclic donor adducts from which the latter represent bisphosphoniotetrylenes. Since dynamic exchange in solution is observed, characterization includes solution and solid-state NMR in addition to SC-XRD, amended by DFT calculations.
Zitierform
In: Chemistry – An Asian Journal Volume 19 / Issue 8 (2023-12-13) eissn:1861-471XFörderhinweis
Gefördert im Rahmen des Projekts DEALGerman Science Fund (DFG) for financial support (CRC 1319 ELCH); János Bolyai Research Scholarship and Project UNKP-23-5 BME-419
Zitieren
@article{doi:10.17170/kobra-2024052410193,
author={Nasemann, Sina and Franz, Roman and Kargin, Denis and Bruhn, Clemens and Kelemen, Zsolt and Gutmann, Torsten and Pietschnig, Rudolf},
title={At the limits of bisphosphonio-substituted stannylenes},
journal={Chemistry – An Asian Journal},
year={2023}
}
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2024-06-21T09:36:17Z 2024-06-21T09:36:17Z 2023-12-13 doi:10.17170/kobra-2024052410193 http://hdl.handle.net/123456789/15866 Gefördert im Rahmen des Projekts DEAL German Science Fund (DFG) for financial support (CRC 1319 ELCH); János Bolyai Research Scholarship and Project UNKP-23-5 BME-419 eng Namensnennung 4.0 International http://creativecommons.org/licenses/by/4.0/ tin lead phosphorus ferrocene tetrylene 540 At the limits of bisphosphonio-substituted stannylenes Aufsatz Donor stabilization of Sn(II) and Pb(II) halides with 1,1’-ferrocenylene bridged bisphosphanes has been explored for Fe(C₅H₄P(C6H₅)₂)₂ (dppf), and Fe(C₅H₄PH(C₄H9))₂. These bisphosphanes are reacted with SnBr₂ and PbCl₂ with and without additional Lewis acid (AlCl₃) forming acyclic and cyclic donor adducts from which the latter represent bisphosphoniotetrylenes. Since dynamic exchange in solution is observed, characterization includes solution and solid-state NMR in addition to SC-XRD, amended by DFT calculations. open access Nasemann, Sina Franz, Roman Kargin, Denis Bruhn, Clemens Kelemen, Zsolt Gutmann, Torsten Pietschnig, Rudolf doi:10.1002/asia.202300950 Grant Number: UNKP-23-5 BME-419 Zinn Blei Phosphor Ferrocen Stannylene publishedVersion eissn:1861-471X Issue 8 Chemistry – An Asian Journal Volume 19 false e202300950
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