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At the limits of bisphosphonio-substituted stannylenes

dc.date.accessioned2024-06-21T09:36:17Z
dc.date.available2024-06-21T09:36:17Z
dc.date.issued2023-12-13
dc.identifierdoi:10.17170/kobra-2024052410193
dc.identifier.urihttp://hdl.handle.net/123456789/15866
dc.description.sponsorshipGefördert im Rahmen des Projekts DEALger
dc.description.sponsorshipGerman Science Fund (DFG) for financial support (CRC 1319 ELCH); János Bolyai Research Scholarship and Project UNKP-23-5 BME-419eng
dc.language.isoeng
dc.rightsNamensnennung 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjecttineng
dc.subjectleadeng
dc.subjectphosphoruseng
dc.subjectferroceneeng
dc.subjecttetryleneeng
dc.subject.ddc540
dc.titleAt the limits of bisphosphonio-substituted stannyleneseng
dc.typeAufsatz
dcterms.abstractDonor stabilization of Sn(II) and Pb(II) halides with 1,1’-ferrocenylene bridged bisphosphanes has been explored for Fe(C₅H₄P(C6H₅)₂)₂ (dppf), and Fe(C₅H₄PH(C₄H9))₂. These bisphosphanes are reacted with SnBr₂ and PbCl₂ with and without additional Lewis acid (AlCl₃) forming acyclic and cyclic donor adducts from which the latter represent bisphosphoniotetrylenes. Since dynamic exchange in solution is observed, characterization includes solution and solid-state NMR in addition to SC-XRD, amended by DFT calculations.eng
dcterms.accessRightsopen access
dcterms.creatorNasemann, Sina
dcterms.creatorFranz, Roman
dcterms.creatorKargin, Denis
dcterms.creatorBruhn, Clemens
dcterms.creatorKelemen, Zsolt
dcterms.creatorGutmann, Torsten
dcterms.creatorPietschnig, Rudolf
dc.relation.doidoi:10.1002/asia.202300950
dc.relation.projectidGrant Number: UNKP-23-5 BME-419
dc.subject.swdZinnger
dc.subject.swdBleiger
dc.subject.swdPhosphorger
dc.subject.swdFerrocenger
dc.subject.swdStannyleneger
dc.type.versionpublishedVersion
dcterms.source.identifiereissn:1861-471X
dcterms.source.issueIssue 8
dcterms.source.journalChemistry – An Asian Journaleng
dcterms.source.volumeVolume 19
kup.iskupfalse
dcterms.source.articlenumbere202300950


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