Discriminatory resonance energy transfer mediated by a chiral environment
| dc.date.accessioned | 2024-08-05T15:05:50Z | |
| dc.date.available | 2024-08-05T15:05:50Z | |
| dc.date.issued | 2024-05-07 | |
| dc.identifier | doi:10.17170/kobra-2024080210633 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/15956 | |
| dc.description.sponsorship | Gefördert im Rahmen eines Open-Access-Transformationsvertrags mit dem Verlag | ger |
| dc.language.iso | eng | |
| dc.rights | Namensnennung 4.0 International | * |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | * |
| dc.subject | chiral | eng |
| dc.subject | energy transfer | eng |
| dc.subject | RET | eng |
| dc.subject | environment | eng |
| dc.subject | macroscopic medium | eng |
| dc.subject | macroscopic QED | eng |
| dc.subject | discrimination | eng |
| dc.subject.ddc | 530 | |
| dc.subject.ddc | 540 | |
| dc.title | Discriminatory resonance energy transfer mediated by a chiral environment | eng |
| dc.type | Aufsatz | |
| dcterms.abstract | In this study, we delve into the crucial influence of and enhancement by chiral environments on the discriminatory capabilities of resonance energy transfer. Firstly, we scrutinize the impact of a macroscopic chiral medium enveloping the interacting molecules; secondly, we probe the effect of a chiral mediating molecule in close proximity to the system. Importantly, our findings demonstrate that chiral environments not only modulate pre-existing discriminatory effects but also introduce novel mechanisms for discrimination. Central to our research is the application of an innovative model for chiral local-field corrections, which unveils a remarkable distance-dependent inversion of the discrimination dynamics. Our study extends beyond the confines of any specific molecular system, offering a comprehensive discussion of these diverse effects, thereby providing insights with broader implications. Finally, we present a comparative analysis across all studied systems, illustrating our insights by employing 3-methyl-cyclopentanone as an example molecule. | eng |
| dcterms.accessRights | open access | |
| dcterms.creator | Franz, Janine Christine | |
| dcterms.creator | Buhmann, Yoshi | |
| dcterms.creator | Salam, Akbar | |
| dc.relation.doi | doi:10.1088/1367-2630/ad3f9c | |
| dc.subject.swd | Chiralität <Chemie> | ger |
| dc.subject.swd | Energieübertragung | ger |
| dc.subject.swd | Resonanzenergie | ger |
| dc.subject.swd | Diskriminierung | ger |
| dc.type.version | publishedVersion | |
| dcterms.source.identifier | eissn:1367-2630 | |
| dcterms.source.journal | New Journal of Physics | eng |
| dcterms.source.volume | Volume 26 | |
| kup.iskup | false | |
| dcterms.source.articlenumber | 053002 |
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