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Dissertation
Untersuchung von Autoionisationsresonanzen in Krypton und Xenon mit photoneninduzierter Fluoreszenzspektroskopie nach Anregung mit schmalbandiger Synchrotronstrahlung
(2009-05-11)
Die photoneninduzierte Fluoreszenzspektroskopie (PIFS) wurde als Methode zur Untersuchung von Fluoreszenzspektren der Edelgasatome Krypton und Xenon nach Anregung mit Synchrotronstrahlung des Elektronenspeicherrings BESSY II, Berlin, benutzt. Die Anregung der Edelgase erfolgte bei Zimmertemperatur und einem Druck von 40mTorr mit extrem schmalbandiger Strahlung mit DeltaE=3meV bei 21,55eV. Die untersuchten Anregungsenergiebereiche waren bei Krypton zwischen 29,4eV und 29,8eV und bei Xenon zwischen 23,74eV und 23,80eV, ...
Dissertation
Zustandsselektive Untersuchung von Anregungs-, Ionisations- und Dissoziationsprozessen in molekularem Wasserstoff mit Fluoreszenzspektroskopie nach Anregung mit schmalbandiger Synchrotronstrahlung
(2011-10-10)
Die Fluoreszenzspektroskopie ist eine der wenigen Methoden, die eine Untersuchung von Zerfallsprozessen nach einer Anregung mit schmalbandiger Synchrotronstrahlung ermöglicht, wenn die Zerfallsprodukte nicht geladen sind. In der vorliegenden Arbeit wurden in erster Linie Anregungen des molekularen Wasserstoffs untersucht, die zur Erzeugung ungeladener aber angeregter Fragmente führten.
Eine Bestimmung der absoluten Querschnitte für die drei möglichen Zerfallskanäle: Ionisation, Dissoziation und molekulare Fluoreszenz ...
Aufsatz
Double photoionization of argon into the {3s3p^5} {^1P}- and {^3P}-states
(1994)
Double photoionization of argon was studied
by photon induced fluorescence spectroscopy (PIFS). Cross sections for the double photoionization into the {3s3p^5} {^1P}, {^3P} states of Ar^{+ +} are presented for exciting photon energies between threshold and 120 eV. In the threshold range the energy dependencies of these cross sections were determined for the first time. Singlet and triplet states are populated with comparable probabilities at equal excess energies, in contrast to predictions of the extended Wannier ...
Aufsatz
Photoionization of Kr 4s: III. Detailed and extended measurements of the Kr 4s-electron ionization cross section
(1994)
Absolute Kr 4s-electron photoionization cross sections as a function of the exciting-photon energy were measured by photon-induced fluorescence spectroscopy (PIFS) at improved primary-energy resolution. The cross sections were determined from threshold to
33.5 eV and to 90 eV with primary-photon bandwidths of 25 meV and 50 meV, respectively. The measurements were compared with experimental data and selected theoretical calculations for the direct Kr 4s-electron photoionization cross sections.
Aufsatz
Delocalization of a hole in van der Waals clusters: Ionization potential of rare-gas and small Hg_n clusters
(American Physical Society, 1993)
The size dependence of the ionization potential I_p(n) of van der Waals (vdW) bound clusters has been calculated by using a model Hamiltonian, which includes electron hopping, vdW interactions, and charge-dipole interactions. The charge-density and dipole-density distributions for both neutral and ionized n-atom clusters are determined self-consistently. The competition between the polarization energy of the neutral atoms surrounding a partially localized hole and the tendency toward hole delocalization in the ionized ...
Aufsatz
Squeezed thermal phonons precurse nonthermal melting of silicon as a function of fluence
(2013)
A femtosecond-laser pulse can induce ultrafast nonthermal melting of various materials along pathways
that are inaccessible under thermodynamic conditions, but it is not known whether there is any structural
modification at fluences just below the melting threshold. Here, we show for silicon that in this regime the
room-temperature phonons become thermally squeezed, which is a process that has not been reported
before in this material. We find that the origin of this effect is the sudden femtosecond-laser-induc ...
Aufsatz
Theoretical study of the structural dependence of nuclear quadrupole frequencies in high-T_c superconductors
(American Physical Society, 1989)
The remarkable difference between the nuclear quadrupole frequencies v_Q of Cu(1) and Cu(2) in YBa_2Cu_3O_6 and YBa_2Cu_3O_7 is analyzed. We calculate the ionic contribution to the electric field gradients and estimate, by using experimental results for Cu_2O and La_2CuO_4, the contribution of the d valence electrons. Thus, we determine v_Q1, v_Q2, and the asymmetry parameter η for YBa_2Cu_3O_6 and YBa_2Cu_3O_7. The number of holes in dthe Cu-O planes and chains is found to be important for the different behavior of ...
Aufsatz
Theory for the Photoacoustic Response to X-Ray Absorption
(American Physical Society, 1988)
A microscopic theory is presented for the photoacoustic effect induced in solids by x-ray absorption. The photoacoustic effect results from the thermalization of the excited Auger electrons and photoelectrons. We explain the dependence of the photoacoustic signal S on photon energy and the proportionality to the x-ray absorption coefficient in agreement with recent experiments on Cu. Results are presented for the dependence of S on photon energy, sample thickness, and the electronic structure of the absorbing solid.