Aufsatz
Model calculations on the influence of quantum electrodynamical effects on the chemistry of superheavy elements.
(The chemistry of element E184)
Zusammenfassung
Using a phenomenological model, the influence of quantum electrodynamical effects on the prediction of the chemical behavior of superheavy elements within a relativistic Dirac-Slater calculation was investigated. This influence will be small and nondetectable for elements up to Z = 114. For elements near Z = 164 some changes in the ground state configurations occur but the chemical behavior will not change. Using this heuristic model, it is also possible to calculate elements beyond Z = 175. As an example we have chosen element E184 and are now able to make more valid speculations about the chemical behavior of the element than Penneman and co-workers could.
Zitierform
In: The journal of chemical physics. - Melville, NY : AIP, 57.1972, S. 371 - 376Zitieren
@article{urn:nbn:de:hebis:34-2008091523803,
author={Fricke, Burkhard and Waber, James Thomas},
title={Model calculations on the influence of quantum electrodynamical effects on the chemistry of superheavy elements.},
year={1972}
}
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2008-09-15T13:11:34Z 2008-09-15T13:11:34Z 1972 0021-9606 urn:nbn:de:hebis:34-2008091523803 http://hdl.handle.net/123456789/2008091523803 541278 bytes application/pdf eng Urheberrechtlich geschützt https://rightsstatements.org/page/InC/1.0/ 530 Model calculations on the influence of quantum electrodynamical effects on the chemistry of superheavy elements. Aufsatz Using a phenomenological model, the influence of quantum electrodynamical effects on the prediction of the chemical behavior of superheavy elements within a relativistic Dirac-Slater calculation was investigated. This influence will be small and nondetectable for elements up to Z = 114. For elements near Z = 164 some changes in the ground state configurations occur but the chemical behavior will not change. Using this heuristic model, it is also possible to calculate elements beyond Z = 175. As an example we have chosen element E184 and are now able to make more valid speculations about the chemical behavior of the element than Penneman and co-workers could. open access The chemistry of element E184 In: The journal of chemical physics. - Melville, NY : AIP, 57.1972, S. 371 - 376 Fricke, Burkhard Waber, James Thomas Extern
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