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dc.date.accessioned2008-10-20T09:47:54Z
dc.date.available2008-10-20T09:47:54Z
dc.date.issued1994
dc.identifier.issn0033-8230
dc.identifier.uriurn:nbn:de:hebis:34-2008102024591
dc.identifier.urihttp://hdl.handle.net/123456789/2008102024591
dc.format.extent482299 bytes
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.subject.ddc530
dc.titleThe electronic structure of the group 6 oxyanions [MO_4]^2-, where M = Cr, Mo, W, and element 106eng
dc.typeAufsatz
dcterms.abstractThe electronic structure of the group 6 oxyanions [MO_4]^2-, where M = Cr, Mo, W, and element 106 have been calculated using the Dirac-Slater Discrete Variational method. Results of the calculations show a relative decrease in the metal-oxygen bond strengths for the [E106O_4]^2- ion in the solid state compared to that for the [WO_4]^2- anion. Calculated energies of the electronic charge-transfer transitions are indicative of a strong possible luminescence of [El06O_4]^2- in the blue-violet area. In solutions [El06O_4]^2- will be the most stable ion out of the entire series. Estimated reduction potential E^0 (El06O^2-_4/E106O^3-_4) equal to -1.60V shows only a slightly increased stability of the +6 oxidation state for element 106 in comparison with W.eng
dcterms.accessRightsopen access
dcterms.bibliographicCitationIn: Radiochimica acta. - Muenchen : Oldenbourg, 65.1994, S. 13-17
dcterms.creatorPershina, Valerija G.
dcterms.creatorFricke, Burkhard


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