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Transformation and Leaching Simulation of 6:2 and 8:2 diPAP and Related Metabolites in Unsaturated Soil Column Studies with MACRO
(2023-10-14)
PFAS (perfluoroalkyl substances) are widespread in the environment and are found in almost every medium. Besides persistent PFAS, their transforming precursors gained attention since they may be a reservoir for persistent PFAS in soil. Only little information is available about the behavior of these precursors and the simultaneous leaching of their transformation products. However, this information is urgently needed to improve estimates of contamination levels. For this purpose, two precursors and their non-degradable ...
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Pectin forms polymeric pigments by complexing anthocyanins during red winemaking and ageing
(2024-05-05)
The long-term stability of red wine color depends on the formation of polymeric pigments from anthocyanins. Although there is still a lot of uncertainty about the specific structure of this diverse group of pigments, there is consensus that they are reaction products of anthocyanins and other polyphenols. Interactions between anthocyanins and pectic polysaccharides have been suggested to stabilize anthocyanins. This study explores the impact of such interactions by adding pectin during red winemaking. The results ...
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Galactosamine and mannosamine are integral parts of bacterial and fungal extracellular polymeric substances
(2024-03-22)
Extracellular polymeric substances (EPS) are produced by microorganisms and interact to form a complex matrix called biofilm. In soils, EPS are important contributors to the microbial necromass and, thus, to soil organic carbon (SOC). Amino sugars (AS) are used as indicators for microbial necromass in soil, although the origin of galactosamine and mannosamine is largely unknown. However, indications exist that they are part of EPS. In this study, two bacteria and two fungi were grown in starch medium either with or ...
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“Stop crying your heart out”: how failed founders can use emotional failure narratives
(2023-06-07)
Failed founders experience very intense emotions resulting from their entrepreneurial failure. Since many founders are not discouraged by failure and consider founding a subsequent startup, the need to deal with the stigma attached to failed founders. Applying an experimental research design, this study investigates how failed founders can use emotional failure narratives to approach potential co-founders for their subsequent venture project. We demonstrate that the use of failure narratives that contain both negative ...
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Machine learning parameter systems, Noether normalisations and quasi-stable positions
(2024-06-25)
We discuss the use of machine learning models for finding “good coordinates” for polynomial ideals. Our main goal is to put ideals into quasi-stable position, as this generic position shares most properties of the generic initial ideal, but can be deterministically reached and verified. Furthermore, it entails a Noether normalisation and provides us with a system of parameters. Traditional approaches use either random choices which typically destroy all sparsity or rather simple human heuristics which are only ...
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Investigations of lightweight concrete by in situ compression tests using high-resolution computed tomography (μ-CT)
(2024-02-24)
The fracture behaviour of concrete is studied in various micro- and macrodamage models. This is important for estimating serviceability and stability of concrete structures. However, a detailed understanding of the material behaviour under load is often not available. In order to better interpret the fracture behaviour and pattern, images of lightweight concrete were taken using a highresolution computed tomography (μ-CT) scanner. The samples were loaded between the taken images and the load was kept constant during ...
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Electron beam powder bed fusion of Ti-30Ta high-temperature shape memory alloy: microstructure and phase transformation behaviour
(2024-06-19)
The present study reports on additive manufacturing of a Ti-30Ta (at.%) high-temperature shape memory alloy (HT-SMA) using electron beam powder bed fusion (PBF-EB/M) technique. Detailed microstructure analysis was conducted to reveal the microstructural evolution along the entire process chain, i.e. from gas-atomised powder to post-processed material. PBF-EB/M processed structures with near full density and an isotropic, β-phase stabilised microstructure, i.e. equiaxed β-grains of around 20 μm in diameter with no ...
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The impact of testosterone-lowering medication on recidivism in individuals convicted of sexual offenses
(2024-06-05)
Introduction: Treatment of individuals who have committed sexual offences with Testosterone-Lowering Medication (TLM) is a comparatively intrusive kind of intervention, which regularly takes place in coercive contexts. Thus, the question of efficacy, but also the question of who should be treated, when and for how long, are of great importance. Methods: Recidivism rates of TLM-treated high-risk individuals (þTLM; n¼54) were compared with high-risk individuals treated with psychotherapy only in the same forensic ...
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Sexuelle Inaktivität und sexuelle Unzufriedenheit bei Paaren in der mittleren Lebensphase nach im Mittel 31 Jahren Beziehungsdauer
(2024-04-30)
Theoretischer Hintergrund. Sexuelle Aktivität und Erleben verändern sich über die Lebensspanne. Unabhängig vom Alter ist ein reduziertes bzw. fehlendes sexuelles Verlangen die am häufigsten berichtete sexuelle Problematik. Es fehlen Studien an Paaren in langjährigen stabilen Partnerschaften. Fragestellung. Ziel war, die sexuelle Inaktivität und Unzufriedenheit von Paaren in der mittleren Lebensphase zu untersuchen. Methode. Es wurden Daten des 18-Jahres Follow-Ups der Längsschnittstudie „Zukunft Familie“ verwendet. ...
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Effect of full-sib and S2-selection on a sweet corn population (Zea mays convar. saccharata)
(2024-04-26)
Sweet corn breeding goals differ from grain or silage corn. Sweet corn goals focus on marketable yield including several quality traits. This study explores the effect of a single cycle of full-sib selection and S2 selection on improving the marketable yield of an open-pollinated sweet corn population. The selected populations were subsequently compared in four environments for several plant-, yield- and quality traits relative to the original population. Analysis of variance was used to detect selection progress and ...