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At the limits of bisphosphonio-substituted stannylenes
(2023-12-13)
Donor stabilization of Sn(II) and Pb(II) halides with 1,1’-ferrocenylene bridged bisphosphanes has been explored for Fe(C₅H₄P(C6H₅)₂)₂ (dppf), and Fe(C₅H₄PH(C₄H9))₂. These bisphosphanes are reacted with SnBr₂ and PbCl₂ with and without additional Lewis acid (AlCl₃) forming acyclic and cyclic donor adducts from which the latter represent bisphosphoniotetrylenes. Since dynamic exchange in solution is observed, characterization includes solution and solid-state NMR in addition to SC-XRD, amended by DFT calculations.
Aufsatz
Investigations of lightweight concrete by in situ compression tests using high-resolution computed tomography (μ-CT)
(2024-02-24)
The fracture behaviour of concrete is studied in various micro- and macrodamage models. This is important for estimating serviceability and stability of concrete structures. However, a detailed understanding of the material behaviour under load is often not available. In order to better interpret the fracture behaviour and pattern, images of lightweight concrete were taken using a highresolution computed tomography (μ-CT) scanner. The samples were loaded between the taken images and the load was kept constant during ...
Aufsatz
Development and Process Integration of an Alternative Demoulding System for High-Pressure Die Casting Using a Contoured Vacuum Mask
(2024-06-11)
This study presents the development and process integration of an alternative demoulding system for high-pressure die casting. The system is aimed at the removal of large structural castings, which are becoming increasingly popular in the industry under the terms mega- and gigacasting. The development differs from conventional systems in the fact that it completely avoids ejectors and realises the demoulding via the principle of vacuum suction cups. Preliminary tests were carried out in which various established ...
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Improving acid-stressed anaerobic digestion processes with biochar towards a combined biomass and carbon management system
(2024-03-06)
Interest in biochar as an additive to enhance anaerobic digestion (AD) has grown in the context of biomass cascading use and the 2050 net-zero goal. However, few studies have investigated the effects of biochar on AD from a biochar production perspective, including biomass feedstocks and pyrolysis temperatures. To valorise biomass and better understand the mechanisms and environmental implications of using biochar in AD, this study investigated the effects of distinct biochar types on AD under acid stress-induced ...
Aufsatz
Personal communication as a strategy to improve the quality of household organic waste – Does it work? results from a quasi-experimental study in Northern Hesse, Germany
(2024-04-22)
Household organic waste has great potential for closing nutrient cycles in agriculture. This requires proper waste separation by households. Personal communication at the doorstep potentially improves household waste separation behaviour but it is expensive and findings from existing research are mixed. Based on results of previous studies and from a quasi-experiment with non-equivalent groups design in two German municipalities, this paper argues that efficiency of personal communication depends on its context. It ...