Suche
Anzeige der Dokumente 161-170 von 233
Aufsatz
Site-specific interrogation of an ionic chiral fragment during photolysis using an X-ray free-electron laser
(2021-08-12)
Short-wavelength free-electron lasers with their ultrashort pulses at high intensities have originated new approaches for tracking molecular dynamics from the vista of specific sites. X-ray pump X-ray probe schemes even allow to address individual atomic constituents with a ‘trigger’-event that preludes the subsequent molecular dynamics while being able to selectively probe the evolving structure with a time-delayed second X-ray pulse. Here, we use a linearly polarized X-ray photon to trigger the photolysis of a ...
Aufsatz
An auxiliary crack approach for efficient approximative crack tip loading analyses
(2021-10-20)
An efficient approach based on the path-independent interaction-integral (I-integral) is suggested for assessing the crack tip loading in elastic structures without having to geometrically model a physical crack. Exploiting just the elastic solution of the uncracked structure, the I-integral is adapted incorporating the closed formulation of crack tip stress and displacement fields of an auxiliary crack, which in this approach is interpreted as hypothetical physical crack. Different specimens and crack configurations ...
Aufsatz
Performance of field-scale lab vs in situ visible/near- and mid-infrared spectroscopy for estimation of soil properties
(2021-10-10)
Comparison of laboratory versus in situ visible/near- (visNIR) and mid-infrared (MIR) spectroscopy for prediction of various soil properties is required to demonstrate trade-offs between accuracy and efficiency. Field measurements were made on an arable field in Germany (silt loam Haplic Luvisol) using visNIR (ASD FieldSpec 3 Hi-Res) and MIR (Agilent Technologies 4300 Handheld FTIR) and material was collected for lab visNIR (Foss XDS Rapid Content Analyzer) and MIR (Bruker-TENSOR 27) measurements on dried and ground ...
Aufsatz
Der innerpsychische Konflikt Individuation vs. Abhängigkeit im Coaching: Zentrale Ergebnisse einer qualitativen Studie zur Praxis erfahrener Coaches
(2021-11-09)
Die unbewusste Dynamik von innerpsychischen Konflikten ist ein wichtiger Inhalt des Erlebens und Verhaltens von Menschen und hat vermutlich einen Einfluss in Coachingprozessen. Diese Studie fokussiert den Grundkonflikt „Individuation vs. Abhängigkeit“ in Einzelcoachings. In einer kleinen qualitativen Feldstudie (n = 13) wurden erfahrene Coaching-Expert/innen zu subjektiven Theorien und präferierten Arbeitskonzepten im Handling dieses Konflikts im Einzelcoaching befragt. Die Inhaltsanalyse zeigt Strategien zum Handling ...
Aufsatz
1,1′-Ferrocenylene-Bridged Bis(N-Heterocyclic Olefin) Derivatives
(2021-10-18)
The 1,1′-ferrocenylene (fc)-bridged bis(N-heterocyclic olefin) compounds (IMes=CH)₂fc (1, IMes=1,3-dimesitylimidazolin-2-ylidene) and (IPr=CH)₂fc (2, IPr=1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) were synthesised from (ICH₂)₂fc (3) and the respective N-heterocyclic carbene IMes or IPr. Ligand substitution reactions of 1 and 2 with [BH₃(THF)] afforded the complexes [1(BH₃)₂] and [2(BH₃)₂] as mixtures of the rac- and meso-diastereomers. The new ferrocene derivatives 1–3 and the complexes meso-[1(BH₃)₂], ...
Aufsatz
A Novel Real Time PCR Method for the Detection and Quantification of Didymella pinodella in Symptomatic and Asymptomatic Plant Hosts
(2021-12-31)
Didymella pinodella is the major pathogen of the pea root rot complex in Europe. This wide host range pathogen often asymptomatically colonizes its hosts, making the control strategies challenging. We developed a real-time PCR assay for the detection and quantification of D. pinodella based on the TEF-1 alpha gene sequence alignments. The assay was tested for specificity on a 54-isolate panel representing 35 fungal species and further validated in symptomatic and asymptomatic pea and wheat roots from greenhouse tests. ...
Aufsatz
Agilität – ein Organisationsmodell für öffentliche Verwaltungen
(2021-07-07)
Dieser Artikel zeigt auf, weshalb das Organisationsmodell Agilität als Reformkonzept für öffentliche Verwaltungen geeignet ist und einen wesentlichen Beitrag zu den noch offenen Themen aus bisherigen Reformen leisten kann. Dies wird entlang den Dimensionen Legitimation (Strategie), Governance (Struktur und Prozesse), Digitalisierung (Technik) und Führung begründet. Führungskräften in öffentlichen Verwaltungen kommt eine zentrale Schlüsselrolle bei den anstehenden Reformen zu. Das Führungsset „Agile Five“, das eine ...
Aufsatz
Identification of a Spatio-Temporal Temperature Model for Laser Metal Deposition
(2021-12-18)
Laser-based additive manufacturing enables the production of complex geometries via layer-wise cladding. Laser metal deposition (LMD) uses a scanning laser source to fuse in situ deposited metal powder layer by layer. However, due to the excessive number of influential factors in the physical transformation of the metal powder and the highly dynamic temperature fields caused by the melt pool dynamics and phase transitions, the quality and repeatability of parts built by this process is still challenging. In order to ...
Aufsatz
Strategic framing of genome editing in agriculture: an analysis of the debate in Germany in the run-up to the European Court of Justice ruling
(2021-10-09)
New techniques in genome editing have led to a controversial debate about the opportunities and uncertainties they present for agricultural food production and consumption. In July 2018, the Court of Justice of the European Union defined genome editing as a new process of mutagenesis, which implies that the resulting organisms count as genetically modified and are subject, in principle, to the obligations of EU Directive 2001/18/EG. This paper examines how key protagonists from academia, politics, and the economy ...
Aufsatz
Das Potenzial kooperativen Lernens ausschöpfen: Die Bedeutung der transaktiven Kommunikation für eine lernwirksame Zusammenarbeit
(2021-10-26)
Kooperatives Lernen eröffnet Chancen und birgt gleichzeitig Risiken für den Wissenserwerb. Der Beitrag arbeitet die Bedeutung der transaktiven Kommunikation als zentralen Wirkmechanismus für den genuinen Mehrwert kooperativen Lernens heraus. Unter transaktiver Kommunikation wird die fachinhaltliche Bezugnahme auf den Lernpartner verstanden, wobei niedrig-transaktive (z.B. paraphrasierende) von hoch-transaktiven (z.B. integrierenden) Äußerungen unterschieden werden. Es werden Bedingungen, unter denen sich transaktive ...