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Performance of field-scale lab vs in situ visible/near- and mid-infrared spectroscopy for estimation of soil properties
(2021-10-10)
Comparison of laboratory versus in situ visible/near- (visNIR) and mid-infrared (MIR) spectroscopy for prediction of various soil properties is required to demonstrate trade-offs between accuracy and efficiency. Field measurements were made on an arable field in Germany (silt loam Haplic Luvisol) using visNIR (ASD FieldSpec 3 Hi-Res) and MIR (Agilent Technologies 4300 Handheld FTIR) and material was collected for lab visNIR (Foss XDS Rapid Content Analyzer) and MIR (Bruker-TENSOR 27) measurements on dried and ground ...
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Der innerpsychische Konflikt Individuation vs. Abhängigkeit im Coaching: Zentrale Ergebnisse einer qualitativen Studie zur Praxis erfahrener Coaches
(2021-11-09)
Die unbewusste Dynamik von innerpsychischen Konflikten ist ein wichtiger Inhalt des Erlebens und Verhaltens von Menschen und hat vermutlich einen Einfluss in Coachingprozessen. Diese Studie fokussiert den Grundkonflikt „Individuation vs. Abhängigkeit“ in Einzelcoachings. In einer kleinen qualitativen Feldstudie (n = 13) wurden erfahrene Coaching-Expert/innen zu subjektiven Theorien und präferierten Arbeitskonzepten im Handling dieses Konflikts im Einzelcoaching befragt. Die Inhaltsanalyse zeigt Strategien zum Handling ...
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1,1′-Ferrocenylene-Bridged Bis(N-Heterocyclic Olefin) Derivatives
(2021-10-18)
The 1,1′-ferrocenylene (fc)-bridged bis(N-heterocyclic olefin) compounds (IMes=CH)₂fc (1, IMes=1,3-dimesitylimidazolin-2-ylidene) and (IPr=CH)₂fc (2, IPr=1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) were synthesised from (ICH₂)₂fc (3) and the respective N-heterocyclic carbene IMes or IPr. Ligand substitution reactions of 1 and 2 with [BH₃(THF)] afforded the complexes [1(BH₃)₂] and [2(BH₃)₂] as mixtures of the rac- and meso-diastereomers. The new ferrocene derivatives 1–3 and the complexes meso-[1(BH₃)₂], ...
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A Critical Review on the Complex Potentials in Linear Elastic Fracture Mechanics
(2022-01-03)
Introducing a crack in an elastic plate is challenging from the mathematical point of view and relevant within an engineering context of evaluating strength and reliability of structures. Accordingly, a multitude of associated works is available to date, emanating from both applied mathematics and mechanics communities. Although considering the same problem, the given complex potentials prove to be different, revealing various inconsistencies in terms of resulting stresses and displacements. Essential information on ...
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A Novel Real Time PCR Method for the Detection and Quantification of Didymella pinodella in Symptomatic and Asymptomatic Plant Hosts
(2021-12-31)
Didymella pinodella is the major pathogen of the pea root rot complex in Europe. This wide host range pathogen often asymptomatically colonizes its hosts, making the control strategies challenging. We developed a real-time PCR assay for the detection and quantification of D. pinodella based on the TEF-1 alpha gene sequence alignments. The assay was tested for specificity on a 54-isolate panel representing 35 fungal species and further validated in symptomatic and asymptomatic pea and wheat roots from greenhouse tests. ...
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Agilität – ein Organisationsmodell für öffentliche Verwaltungen
(2021-07-07)
Dieser Artikel zeigt auf, weshalb das Organisationsmodell Agilität als Reformkonzept für öffentliche Verwaltungen geeignet ist und einen wesentlichen Beitrag zu den noch offenen Themen aus bisherigen Reformen leisten kann. Dies wird entlang den Dimensionen Legitimation (Strategie), Governance (Struktur und Prozesse), Digitalisierung (Technik) und Führung begründet. Führungskräften in öffentlichen Verwaltungen kommt eine zentrale Schlüsselrolle bei den anstehenden Reformen zu. Das Führungsset „Agile Five“, das eine ...
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Multi-Objective Optimal Design and Development of a Four-Bar Mechanism for Weed Control
(2022-03-09)
Weeds compete with crops for water, nutrients, and light consequently, have adverse effects on the crop yield and overall productivity. Mechanical weeding is the most common non-chemical method for weed control, which is applied in organic farming, and the weed cultivator is the most common implement in mechanical weeding. This study aimed to design and develop an innovative active tool to optimize the cultivation depth, which can avoid damage to crop roots and improve the key performance indicators of an inter-row ...
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Lie algebra for rotational subsystems of a driven asymmetric top
(2022-05-11)
We present an analytical approach to construct the Lie algebra of finite-dimensional subsystems of the driven asymmetric top rotor. Each rotational level is degenerate due to the isotropy of space, and the degeneracy increases with rotational excitation. For a given rotational excitation, we determine the nested commutators between drift and drive Hamiltonians using a graph representation. We then generate the Lie algebra for subsystems with arbitrary rotational excitation using an inductive argument.
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Reversible Photo-Induced Reshaping of Imprinted Microstructures Using a Low Molecular Azo Dye
(2022-01-31)
A blend of low molecular azo glass (AZOPD) and polystyrene (PS) were used for the systematic investigation of photo-induced stretching and recovery of nanoimprinted structures. For this purpose, light and heat was used as recovery stimuli. The AZOPD/PS microstructures, fabricated with thermal nanoimprint lithography (tNIL), comprises three different shapes (circles, crosses and squares) and various concentrations of AZOPD fractions. The results show a concentrationdependent reshaping. Particularly the sample with 43 ...
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Identification of a Spatio-Temporal Temperature Model for Laser Metal Deposition
(2021-12-18)
Laser-based additive manufacturing enables the production of complex geometries via layer-wise cladding. Laser metal deposition (LMD) uses a scanning laser source to fuse in situ deposited metal powder layer by layer. However, due to the excessive number of influential factors in the physical transformation of the metal powder and the highly dynamic temperature fields caused by the melt pool dynamics and phase transitions, the quality and repeatability of parts built by this process is still challenging. In order to ...