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Influence of Chitosan and Grape Seed Extract on Thermal and Mechanical Properties of PLA Blends
(2023-03-22)
Blends based on polylactic acid (PLA), chitosan, and grape seed extract (GE) were prepared by extrusion and injection molding. The effect of chitosan (5% and 15% on PLA basis) and natural extract (1% on PLA basis) incorporated into the PLA host matrix was explored regarding the thermal and mechanical properties. GE showed antioxidant activity, as determined by the DPPH assay method. Chitosan and GE affect the degree of crystallinity up to 30% as the polysaccharide acts as a nucleating agent, while the extract reduces ...
Aufsatz
Gradual Coordination and Reversible P–P Bond Activation of a P3-Unit with Transition Metal Carbony
(2024-03-20)
Coordination of a stereochemically defined P3-chain to a series of transition metal carbonyls [M(CO)x]z− (M = Mn (x = 5, z = 1), Fe (x = 4, z = 2) or Co (x = 4, z = 1)) is explored using a 3]ferrocenophane scaffold. A gradual transition from 𝜼1-, 𝜼2- to 𝜼3-coordination is observed where in the 𝜼2-mode the terminal positions of the phosphorus chain are bridged. With an excess of cobalt carbonyl successive P–P bond activation and gradual separation of the central phosphorus atoms from the phosphorus chain has been ...
Aufsatz
On the Influence of Microstructure on the Corrosion Behavior of Fe–Mn–Al–Ni Shape Memory Alloy in 5.0 wt% NaCl Solution
(2020-10-03)
Herein the corrosion behavior of Fe–Mn–Al–Ni shape memory alloys characterized by different microstructures in a 5.0 wt% NaCl solution is investigated. Open circuit potential and potentiodynamic polarisation tests are conducted. Generally, Fe–Mn–Al–Ni shows corrosion properties being similar to pure iron. However, the polarization curves of single crystals indicate the presence of an unstable passive system. The corrosion damage is analyzed by means of optical microscopy and electron microscopy. It is revealed that ...