Search
Now showing items 181-190 of 192
Aufsatz
Chalcogen‐Transfer Rearrangement: Exploring Inter‐ versus Intramolecular P−P Bond Activation
(2020-07-17)
tert‐Butyl‐substituted diphospha[2]ferrocenophane has been used as a stereochemically confined diphosphane to explore the addition of O, S, Se and Te. Although the diphosphanylchalcogane has been obtained for tellurium, all other chalcogens give diphosphane monochalcogenides. The latter transform via chalcogen‐transfer rearrangement to the corresponding diphosphanylchalcoganes upon heating. The kinetics of this rearrangement has been followed with NMR spectroscopy supported by DFT calculations. Intermediates during ...
Aufsatz
Spontaneous inferential processing while reading interleaved expository texts enables learners to discover the underlying regularities
(2020-11-05)
Recent studies on text sequencing found learning advantages of interleaving over blocking in terms of high‐level inferences. We conducted a 2 × 2 × 2 mixed factorial experiment with college students (n = 117) by manipulating text sequence (interleaved vs. blocked) and self‐questioning activity while reading (spontaneous vs. prompted) between subjects and testing delay (immediately vs. 1‐week delay) within subjects. Results revealed that students are spontaneously engaged in self‐questioning and inferential processing ...
Aufsatz
Are criminals better lie detectors? Investigating offenders' abilities in the context of deception detection
(2020-10-24)
The present research examined lie detection abilities of a rarely investigated group, namely offenders. Results of the studies conducted thus far indicated a better performance of offenders compared to non‐offenders when discriminating between true and false messages. With two new studies, we aimed at replicating offenders' superior abilities in the context of deception detection. Results of Study 1 (N = 76 males), in contrast, revealed that offenders were significantly worse at accurately classifying true and false ...
Aufsatz
How to run a sustainability science research group sustainably?
(2020-08-25)
Rigorous sustainability science includes addressing pressing real-world problems, weaving multiple knowledge systems, and striving for transformative change. However, these key attributes of sustainability science often conflict with university structures and established academic work practices, for instance with regard to frequent long-distance travel. Such contradictions between key principles of sustainability and everyday practices are experienced by many researchers not only at university level, but also in their ...
Aufsatz
Temperature resistant fast InxGa1−xAs / GaAs quantum dot saturable absorber for the epitaxial integration into semiconductor surface emitting lasers
(2020-06-30)
Quantum-dot-based semiconductor saturable absorber mirrors (SESAMs) with fast response times were developed by molecular beam epitaxy (MBE). Using quantum dots (QDs) in the absorber region of the SESAMs instead of quantum wells, enables additional degrees of freedom in the design, the control of saturation parameters and the recovery dynamics. However, if one wants to integrate such a SESAM element into semiconductor surface emitting lasers such as a mode-locked integrated external-cavity surface-emitting laser ...
Aufsatz
An interdisciplinary assessment of private conservation areas in the Western United States
(2020-02-20)
Conservation easements are the fastest growing private conservation strategy in the United States. However, mechanisms to assess private land conservation as well as their support by the general public are not well understood. This study uses the ecosystem services framework for assessing existing private lands in Idaho and identifies areas for future conservation easements. Using conservation targets of the land trust as a guide for selecting ecosystem services, we (a) mapped the spatial delivery of conservation ...
Aufsatz
Genetic diversity and differentiation of Olea europaea subsp. cuspidata (Wall. & G.Don) Cif. in the Hajar Mountains of Oman
(2020-10-04)
Olea europaea subsp. cuspidata (Wall. & G. Don) Cif. is one of the six subspecies important for domestication of olive described as having valuable breeding traits. It is distributed from South Africa to the Middle East and the Mediterranean region to China mainly at mid to high altitudes with adequate precipitation. The currently rather fragmented Olea europaea subsp. cuspidata populations likely represent outposts of a formerly larger and more connected area and are hence vulnerable to additional stresses such as ...
Aufsatz
The J-integral for mixed-mode loaded cracks with cohesive zones
(2020-11-23)
The J-integral quantifies the loading of a crack tip, just as the crack tip opening displacement (CTOD) emanating from the cohesive zone model. Both quantities, being based on fundamentally different interpretations of cracks in fracture mechanics of brittle or ductile materials, have been proven to be equivalent in the late 60s of the previous century, however, just for the simple mode-I loading case. The relation of J and CTOD turned out to be uniquely determined by the constitutive law of the cohesive zone in front ...
Aufsatz
Heat Pump Bridge Analysis using the Modified Energy Transfer Diagram
(2020-12-29)
Heat pumps are the key technology to decarbonise thermal processes by upgrading industrial surplus heat using renewable electricity. Existing insight-based integration methods refer to the idealised Grand Composite Curve requiring the full exploitation of heat recovery potential but leave the question of how to deal with technical or economic limitations unanswered. In this work, a novel Heat Pump Bridge Analysis (HPBA) is introduced for practically targeting technical and economic heat pump potential by applying ...
Aufsatz
Managing Rangelands Without Herding? Insights From Africa and Beyond
(2020-12-11)
In many parts of the world, the utilization of rangelands is based on the targeted movement of herds within and across often vast territories. Crucial for the success of these livestock operations are decisions on how to flexibly allocate animals to the existing vegetation, both in terms of numbers and concentrations, and in space and time. Research from large scale ranching in the prairies of the Americas, and nomadic or transhumant livestock systems in Africa, the Middle East, and Central Asia, suggests that the ...