Aufsatz
Artikel (Publikationen im Open Access gefördert durch die UB)
Preparation and Molecular Structure of a Cyclopentyl-Substituted Cage Hexasilsesquioxane T6 (T = cyclopentyl-SiO1.5) Starting from the Corresponding Silanetriol
Zusammenfassung
Cyclopentyl substituted silanetriol can be prepared and isolated. Its condensation yields the corresponding disiloxanetetrol as a primary condensation product. Further condensation leads to the hexameric polyhedral silsesquioxane cage T6. The latter has been mentioned in the literature before however, lacking structural data. All compounds have been characterized with multinuclear NMR spectroscopy and, in addition, the molecular structures have been determined in the case of the disiloxanetetrol and the hexasilsesquioxane via single crystal X-ray diffraction.
Zitierform
In: Inorganics. - Basel : MDPI. - 2017, 5(4), 66, 1-8Förderhinweis
Gefördert durch den Publikationsfonds der Universität KasselSammlung(en)
Publikationen (Arbeitsgruppe Chemische Hybridmaterialien)Artikel (Publikationen im Open Access gefördert durch die UB)
Zitieren
@article{urn:nbn:de:hebis:34-2018020254389,
author={Kahr, Jürgen and Belaj, Ferdinand and Pietschnig, Rudolf},
title={Preparation and Molecular Structure of a Cyclopentyl-Substituted Cage Hexasilsesquioxane T6 (T = cyclopentyl-SiO1.5) Starting from the Corresponding Silanetriol},
year={2017}
}
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2018-02-02T14:05:09Z 2018-02-02T14:05:09Z 2017-10-04 2304-6740 urn:nbn:de:hebis:34-2018020254389 http://hdl.handle.net/123456789/2018020254389 Gefördert durch den Publikationsfonds der Universität Kassel eng Urheberrechtlich geschützt https://rightsstatements.org/page/InC/1.0/ silanetriols disiloxane tetrols silsesquioxanes condensation molecular cage 540 Preparation and Molecular Structure of a Cyclopentyl-Substituted Cage Hexasilsesquioxane T6 (T = cyclopentyl-SiO1.5) Starting from the Corresponding Silanetriol Aufsatz Cyclopentyl substituted silanetriol can be prepared and isolated. Its condensation yields the corresponding disiloxanetetrol as a primary condensation product. Further condensation leads to the hexameric polyhedral silsesquioxane cage T6. The latter has been mentioned in the literature before however, lacking structural data. All compounds have been characterized with multinuclear NMR spectroscopy and, in addition, the molecular structures have been determined in the case of the disiloxanetetrol and the hexasilsesquioxane via single crystal X-ray diffraction. open access In: Inorganics. - Basel : MDPI. - 2017, 5(4), 66, 1-8 Kahr, Jürgen Belaj, Ferdinand Pietschnig, Rudolf doi:10.3390/inorganics5040066
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:Urheberrechtlich geschützt