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dc.date.accessioned2018-02-02T14:05:09Z
dc.date.available2018-02-02T14:05:09Z
dc.date.issued2017-10-04
dc.identifier.issn2304-6740
dc.identifier.uriurn:nbn:de:hebis:34-2018020254389
dc.identifier.urihttp://hdl.handle.net/123456789/2018020254389
dc.description.sponsorshipGefördert durch den Publikationsfonds der Universität Kassel
dc.language.isoeng
dc.subjectsilanetriolseng
dc.subjectdisiloxane tetrolseng
dc.subjectsilsesquioxaneseng
dc.subjectcondensationeng
dc.subjectmolecular cageeng
dc.subject.ddc540
dc.titlePreparation and Molecular Structure of a Cyclopentyl-Substituted Cage Hexasilsesquioxane T6 (T = cyclopentyl-SiO1.5) Starting from the Corresponding Silanetrioleng
dc.typeAufsatz
dcterms.abstractCyclopentyl substituted silanetriol can be prepared and isolated. Its condensation yields the corresponding disiloxanetetrol as a primary condensation product. Further condensation leads to the hexameric polyhedral silsesquioxane cage T6. The latter has been mentioned in the literature before however, lacking structural data. All compounds have been characterized with multinuclear NMR spectroscopy and, in addition, the molecular structures have been determined in the case of the disiloxanetetrol and the hexasilsesquioxane via single crystal X-ray diffraction.eng
dcterms.accessRightsopen access
dcterms.bibliographicCitationIn: Inorganics. - Basel : MDPI. - 2017, 5(4), 66, 1-8
dcterms.creatorKahr, Jürgen
dcterms.creatorBelaj, Ferdinand
dcterms.creatorPietschnig, Rudolf
dc.relation.doidoi:10.3390/inorganics5040066


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