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Dissertation
Testing the Impact of Large-scale Digital Support on Students' Paths Toward College Education
(2024-02)
Increasing the share of college graduates can boost productivity, promote social mobility, and improve well-being. However, these benefits are often realized when the education system satisfies the demands of the industry. Otherwise, society may face skill shortages. This thesis aims to expand the understanding of how to attract students, particularly minorities, to pursue academic majors linked to the areas facing skill shortages (henceforth, high-rewarding majors). To accomplish this, it examines the impact of ...
Dissertation
Reporting Power
(2024)
An eclectic genealogy (Foucault, 1977) that reconstructs the previous understanding and emergence of a ‘taken for granted’ global practice: the practice of suspicious activity reporting. A governance practice whereby financial institutions worldwide document and report the conduct of consumers deemed suspicious. At the center of this practice is a material artefact, a multipage fillable form called the Suspicious Activity Report. Following Actor-Network Theory (Latour, 1987), the form also serves as the centerpiece ...
Dissertation
Towards the investigation of ultrafast dynamics in chiral systems using free-electron lasers
(2024)
Chiral molecules are life’s building blocks, making the study of their ultrafast processes a pursuit across various fundamental research fields. The results presented in this dissertation contain methodological, technical and scientific advancements that pave the way for future time-resolved, site-specific investigations into chiral photochemistry of randomly orientated molecules, using photoelectron circular dichroism and free-electron lasers. The high-repetitionrate free-electron lasers EuXFEL and FLASH2 will soon ...
Dissertation
Context Awareness for Smartphone-Based Cooperative VRU Collision Avoidance
(2024)
Nach Angaben der Weltgesundheitsorganisation sterben weltweit noch immer jährlich rund 1,35 Millionen Menschen bei Verkehrsunfällen. Ungefähr 54% dieser Todesfälle ereignen sich unter ungeschützten Verkehrsteilnehmern wie Fußgängern, Radfahrern und Motorradfahrern. Fußgänger und Radfahrer machen dabei zusammen rund 26% aller Verkehrstoten aus. Im Gegensatz zu fahrzeugbasierten Kollisionsvermeidungssystemen setzen kooperative Systeme die Verwendung von mobilen Geräten wie Smartphones zur kontinuierlichen Erfassung von ...
Dissertation
Multifinalität von Verlust- und Trennungserfahrungen in der frühen Adoleszenz
(2022)
Zahlreiche Erkenntnisse aus den bisherigen Untersuchungen zu den langfristigen Auswirkungen einer Scheidung auf die Kinder konvergieren in der Einsicht, dass eine elterliche Trennung mit negativen psychosozialen Folgen einhergehen kann, dies jedoch nicht zwangsläufig muss. Ein einheitliches Muster von Scheidungsfolgen konnte bisher nicht gefunden werden. So zeigten bisherige Studien, dass die individuellen Trennungsverläufe und die damit einhergehenden Stressoren aber auch Ressourcen der Kinder und Familien die ...
Dissertation
The anatomy of velvet worms (Onychophora) as revealed by a multimethodological approach and three-dimensional reconstructions
(2024)
Onychophorans, or velvet worms, comprise a small group of worm-like, multi-legged terrestrial invertebrates. Since their discovery in 1826, these organisms have been investigated from different perspectives, particularly in the field of morphology—a discipline that provides the basis for functional and evolutionary inferences. Onychophorans are currently classified within Ecdysozoa (moulting animals) and form together with Tardigrada (water bears) and Arthropoda a clade named Panarthropoda. Therefore, onychophorans ...
Dissertation
Pentamethylcyclopentadienyl-Halbsandwich-Eisenkomplexe mit ungewöhnlichen Carbenliganden
(2024)
This dissertation project deals with the electronic properties of the pentamethylcyclopentadienyl halfsandwich iron complex with bis(trimethylsilyl)amido ligand ([Fe(Cp*)(HMDS)], HMDS = N(SiMe₃)₂) and its reactivity towards carbenes or their direct precursor compounds. The compound was published in 1998 by the Siemeling group and described at the time as diamagnetic. Structurally very similar representatives with penta-isopropylcyclopentadienyl- (⁵Cp) and 1,2,4-tri-tert-butylcyclopentadienyl ligands (Cp‘) have been ...
Dissertation
Die Synthese planar-chiraler 1,1´–Diaminoferrocenderivate
(2024)
Dieses Forschungsprojekt beschäftigt sich mit 1,1´-Diaminoferrocenderivaten, die aufgrund ei-nes weiteren Substituenten X in Nachbarstellung (ortho-Position) zu einer der Stickstoffgrup-pen planare Chiralität aufweisen. Obgleich 1,1´-Diaminoferrocen eine bewährte Schlüsselver-bindung innerhalb der Ferrocenchemie ist, insbesondere zur Darstellung von N,N-Chelatligan-den und N-heterozyklischen Tetrylenen, jeweils mit 1,1´-Ferrocenylenrückgrat, war der syn-thetische Zugang zu den hier behandelten planar-chiralen ...
Dissertation
Existence and Asymptotic Behavior of Solutions to the Time-Periodic Navier-Stokes Equations in a Layer Domain with Nonhomogeneous Boundary Data
(2024)
This dissertation is dedicated to the analysis of the Navier-Stokes equations in a timeperiodic framework in the so-called layer domain Π = R2 × (0, 1), described by:
∂tu − νΔu + (u · ∇)u + ∇p = f in [0, T] × Π,
div u = 0 in [0, T] × Π,
u|∂Π = a for all t ∈ [0, T] ,
u|t=0 = u|t=T in Π.
The velocity field u and the pressure p are unknowns, while the external force f is prescribed. Challenges arise due to unboundedness of the layer Π and from introduction of a nonhomogeneous boundary condition a. The investigated ...
Dissertation
City Development Regimes in-the-Making. Phronetic Analysis of Governance, Networks and Power in Cairo, 2011-2022
(2024)
Since the revolutionary uprising of January 2011, Cairo’s inner-city neighbourhoods have undergone rapid spatial transformations. Over the last decade, numerous old housing buildings have been replaced by modern ones, leading to the displacement of residents to the desert cities or newly-constructed neighbourhoods outside the city centre. The most remarkable transformations occurred since early 2018. Notably, these changes have been characterised by a fast implementation rate and a lack of community resistance to ...