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Metallated [3]Ferrocenophanes Containing P3M Bridges (M = Li, Na, K)

Isenberg, Stefan
Frenzel, Lisa-Marie
Bruhn, Clemens
Pietschnig, Rudolf

Alkali-metal phosphanides can be embedded into a [3]ferrocenophane scaffold giving rise to bicyclic ferrocenophanes [MFe(C5H4PtBu)2P] (M = Li, Na, K). Coordination of the alkali-metal ions takes place via the terminal phosphorus atoms adopting a puckered P3M four-membered ring. All compounds were characterized via single-crystal X-ray diffraction and multinuclear NMR spectroscopy (1H, 31P, 7Li), whereas 13C NMR data could only be recorded for the Li derivative, owing to the limited solubility of its heavier congeners in unreactive solvents.

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Gefördert durch den Publikationsfonds der Universität Kassel 
@article{urn:nbn:de:hebis:34-2018081756090,
  author    ={Isenberg, Stefan and Frenzel, Lisa-Marie and Bruhn, Clemens and Pietschnig, Rudolf},
  title    ={Metallated [3]Ferrocenophanes Containing P3M Bridges (M = Li, Na, K)},
  copyright  ={https://rightsstatements.org/page/InC/1.0/},
  language ={en},
  year   ={2018-07-11}
}