Metallated [3]Ferrocenophanes Containing P3M Bridges (M = Li, Na, K)

dc.date.accessioned2018-08-17T14:48:22Z
dc.date.available2018-08-17T14:48:22Z
dc.date.issued2018-07-11
dc.description.sponsorshipGefördert durch den Publikationsfonds der Universität Kassel
dc.identifier.issn2304-6740
dc.identifier.uriurn:nbn:de:hebis:34-2018081756090
dc.identifier.urihttp://hdl.handle.net/123456789/2018081756090
dc.language.isoeng
dc.relation.doidoi:10.3390/inorganics6030067
dc.rightsUrheberrechtlich geschützt
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/
dc.subjectalkali metaleng
dc.subjectphosphoruseng
dc.subjectferrocenophaneeng
dc.subjectphosphideeng
dc.subjectphosphanideeng
dc.subject.ddc540
dc.titleMetallated [3]Ferrocenophanes Containing P3M Bridges (M = Li, Na, K)eng
dc.typeAufsatz
dcterms.abstractAlkali-metal phosphanides can be embedded into a [3]ferrocenophane scaffold giving rise to bicyclic ferrocenophanes [MFe(C5H4PtBu)2P] (M = Li, Na, K). Coordination of the alkali-metal ions takes place via the terminal phosphorus atoms adopting a puckered P3M four-membered ring. All compounds were characterized via single-crystal X-ray diffraction and multinuclear NMR spectroscopy (1H, 31P, 7Li), whereas 13C NMR data could only be recorded for the Li derivative, owing to the limited solubility of its heavier congeners in unreactive solvents.eng
dcterms.accessRightsopen access
dcterms.bibliographicCitationIn: Inorganics. - Basel : MDPI. - 2018, 6(3), 67, 1-9
dcterms.creatorIsenberg, Stefan
dcterms.creatorFrenzel, Lisa-Marie
dcterms.creatorBruhn, Clemens
dcterms.creatorPietschnig, Rudolf

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