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Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes

dc.date.accessioned2022-08-22T14:01:57Z
dc.date.available2022-08-22T14:01:57Z
dc.date.issued2022-05-24
dc.identifierdoi:10.17170/kobra-202208196705
dc.identifier.urihttp://hdl.handle.net/123456789/14090
dc.description.sponsorshipGefördert durch den Publikationsfonds der Universität Kasselger
dc.language.isoengeng
dc.rightsNamensnennung 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectorganophosphorus chemistryeng
dc.subjectluminescenceeng
dc.subjectcoinage metaleng
dc.subjectcoordination chemistryeng
dc.subjectchiralityeng
dc.subject.ddc540
dc.titleAsymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexeseng
dc.typeAufsatz
dcterms.abstractA series of coinage metal complexes asymmetrically substituted 2,5-diaryl phosphole ligands is reported. Structure, identity, and purity of all obtained complexes were corroborated with state-of-the-art techniques (multinuclear NMR, mass spectrometry, elemental analysis, X-ray diffraction) in solution and solid state. All complexes obtained feature luminescence in solution as well as in the solid state. Additionally, DOSY-MW NMR estimation experiments were performed to achieve information about the aggregation behavior of the complexes in solution allowing a direct comparison with their structures observed in the solid state.eng
dcterms.accessRightsopen access
dcterms.creatorRoesler, Fabian
dcterms.creatorBruhn, Clemens
dcterms.creatorPietschnig, Rudolf
dc.relation.doidoi:10.3390/molecules27113368
dc.subject.swdPhosphororganische Verbindungenger
dc.subject.swdLumineszenzger
dc.subject.swdMünzmetallger
dc.subject.swdKoordinationslehreger
dc.subject.swdChiralität <Chemie>ger
dc.type.versionpublishedVersion
dcterms.source.identifiereissn:1420-3049
dcterms.source.issueIssue 11
dcterms.source.journalMoleculeseng
dcterms.source.volumeVolume 27
kup.iskupfalse
dcterms.source.articlenumber3368


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