Datum
2022-06-28Schlagwort
660 Chemische Verfahrenstechnik, Technische Chemie ElektrolytPolyurethaneKunststoffverarbeitungChemische ReaktionElektrochemiePolyelektrolytAggregatzustandIonenleitungPolyethylenglykoleMetadata
Zur Langanzeige
Aufsatz
Polyurethane-Based Gel Electrolyte for Application in Flexible Electrochromic Devices
Zusammenfassung
For the application in flexible electrochromic devices (ECDs) on plastic substrates, a new polyurethane-based gel electrolyte was manufactured. In this context, the curing behavior and the influence of the proportion of solvent and salt on the ion conductivity as well as the optical and mechanical properties were investigated. Furthermore, the stoichiometric ratio of the polyurethane matrix was varied to influence the ion conductivity. As an isocyanate component, the aliphatic difunctional polyisocyanate prepolymer, synthesized by Hexamethylen-1,6-diisocyanat (HDI), was chosen since the resulting polyurethane is considered to be particularly lightfast, color-stable and temperature-resistant and therefore frequently used for paints and coatings. As polyol a trifunctional polyetherpolyol was selected to form a wide-meshed crosslinked matrix to achieve a mechanically stable but flexible electrolyte, that enables the processing and bending of film-based ECDs. The additives amount and the matrix stoichiometric ratio affected the curing behavior and curability. The salt content had almost no influence on the measured properties in the chosen experimental space. Solvent content had a great influence on ion conductivity and mechanical properties. An understoichiometric ratio of the polyurethane matrix (0.85) increases the ion conductivity and the mechanical flexibility, but also the optical properties in a negative manner. The best specific ion conductivity with 10-⁵ S/cm was reached with an understoichiometric ratio of 0.85 and a high solvent content (30 wt%). Concluding, due to its high flexibility and transmittance, color neutrality and sufficient ion conductivity, the application of the researched electroyte in ECDs might be suitable. A demonstrator ECD was successfully manufactured and conducted.
Zitierform
In: Polymers Volume 14 / Issue 13 (2022-06-28) eissn:2073-4360Förderhinweis
Gefördert durch den Publikationsfonds der Universität KasselZitieren
@article{doi:10.17170/kobra-202208236733,
author={Johannes, Christopher and Hartung, Michael and Heim, Hans-Peter},
title={Polyurethane-Based Gel Electrolyte for Application in Flexible Electrochromic Devices},
journal={Polymers},
year={2022}
}
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2022-08-24T07:37:36Z 2022-08-24T07:37:36Z 2022-06-28 doi:10.17170/kobra-202208236733 http://hdl.handle.net/123456789/14099 Gefördert durch den Publikationsfonds der Universität Kassel eng Namensnennung 4.0 International http://creativecommons.org/licenses/by/4.0/ electrolyte electrochromic device flexible 660 Polyurethane-Based Gel Electrolyte for Application in Flexible Electrochromic Devices Aufsatz For the application in flexible electrochromic devices (ECDs) on plastic substrates, a new polyurethane-based gel electrolyte was manufactured. In this context, the curing behavior and the influence of the proportion of solvent and salt on the ion conductivity as well as the optical and mechanical properties were investigated. Furthermore, the stoichiometric ratio of the polyurethane matrix was varied to influence the ion conductivity. As an isocyanate component, the aliphatic difunctional polyisocyanate prepolymer, synthesized by Hexamethylen-1,6-diisocyanat (HDI), was chosen since the resulting polyurethane is considered to be particularly lightfast, color-stable and temperature-resistant and therefore frequently used for paints and coatings. As polyol a trifunctional polyetherpolyol was selected to form a wide-meshed crosslinked matrix to achieve a mechanically stable but flexible electrolyte, that enables the processing and bending of film-based ECDs. The additives amount and the matrix stoichiometric ratio affected the curing behavior and curability. The salt content had almost no influence on the measured properties in the chosen experimental space. Solvent content had a great influence on ion conductivity and mechanical properties. An understoichiometric ratio of the polyurethane matrix (0.85) increases the ion conductivity and the mechanical flexibility, but also the optical properties in a negative manner. The best specific ion conductivity with 10-⁵ S/cm was reached with an understoichiometric ratio of 0.85 and a high solvent content (30 wt%). Concluding, due to its high flexibility and transmittance, color neutrality and sufficient ion conductivity, the application of the researched electroyte in ECDs might be suitable. A demonstrator ECD was successfully manufactured and conducted. open access Johannes, Christopher Hartung, Michael Heim, Hans-Peter doi:10.3390/polym14132636 Elektrolyt Polyurethane Kunststoffverarbeitung Chemische Reaktion Elektrochemie Polyelektrolyt Aggregatzustand Ionenleitung Polyethylenglykole publishedVersion eissn:2073-4360 Issue 13 Polymers Volume 14 false 2636
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